Oil-Based Filter Cake Removal Using Mutual Solvent Precursors

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

The presence of filter cakes on subterranean formation faces, particularly in injection wells, hinders fluid flow and requires high pump pressures, making it difficult to achieve efficient oil recovery, especially in deepwater environments.

Innovation Solution

A wellbore servicing method using compositions comprising a mutual solvent precursor, an acid precursor, and an aqueous fluid to convert oil-wet solids to water-wet solids, allowing for the delayed removal of oil-based filter cakes, thereby reducing the need for high injection pressures and improving fluid flow efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If high pump pressures are used to inject fluid past the filter cake, then fluid flow through the injection well is achieved, but the pump pressures exceed desirable levels and sweep efficiency is reduced

Engineering Contradiction:
Improvefluid flow efficiencyVSAvoidpump pressure
Core Design Contradiction:
Ease of operationVSStress or pressure

Solution Approach 1:

The patent applies preliminary action by treating the filter cake with a chemical composition before the injection flood operation. The composition containing mutual solvent precursor, acid precursor, and aqueous fluid is introduced into the wellbore to convert the filter cake from oil-wet to water-wet state in advance, reducing the pressure required for subsequent fluid injection and improving sweep efficiency

Inventive Principle:
Principle #10Preliminary action

2Reliability

If a filter cake is present on the formation face, then drilling and fluid loss prevention are improved, but fluid flow through injection and production wells is hindered

Engineering Contradiction:
Improvedrilling success and fluid loss preventionVSAvoidfluid flow
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The patent applies parameter changes by altering the wettability parameter of the filter cake through chemical treatment. The composition changes the surface properties of the filter cake from oil-wet to water-wet, transforming it from a flow barrier to a permeable medium that allows efficient fluid injection and production

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method effectively removes oil-based filter cakes in a time-delayed fashion, enhancing fluid flow and reducing the risk of formation damage, allowing for more efficient oil recovery operations.

Implementation Method 1

contacting the oil wet solids in the wellbore with a composition comprising a mutual solvent precursor; an acid precursor and an aqueous fluid

Methodology Applied
Scientific EffectHydrolysis: Hydrolysis

Implementation Method 2

allowing the oil wet solids to become water wet

Methodology Applied
Scientific EffectWetting: Wetting

Implementation Method 3

wherein the formic acid catalyzes the hydrolysis of additional formate ester

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 4

wherein the formate ester hydrolyzes to release formic acid

Methodology Applied
Scientific EffectHydrolysis: Hydrolysis

Data Source

PatentUS7906464B2Compositions and methods for the removal of oil-based filtercakes
Publication Date: 2011.03.15 HALLIBURTON ENERGY SERVICES INC
  • US7906464B2 patent drawing

AI summary

A method of servicing a wellbore comprising providing a composition comprising a mutual solvent precursor, an acid precursor, and an aqueous fluid, and contacting the composition with oil wet solids in the wellbore. A method of servicing a wellbore comprising introducing an oil-based fluid into a wellbore, wherein the oil-based fluid forms oil wet solids in the wellbore, contacting the oil wet solids in the wellbore with a composition comprising a mutual solvent precursor; an acid precursor and an aqueous fluid, and allowing the oil wet solids to become water wet. A method of servicing a well bore comprising contacting a composition comprising a formate ester with oil wet solids in the well bore under conditions wherein the formate ester hydrolyzes to release formic acid, wherein the formic acid catalyzes the hydrolysis of additional formate ester, and wherein all or a portion of the formate ester converts at least a portion of the oil-wet solids to water-wet solids.