Oil-Based Inkjet Ink Discharge Stability and Show-Through

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Solution Overview

Problem

Existing oil-based inkjet inks face issues with discharge stability after a long idle period and show-through in printed items due to nozzle adhesion and volatility, as well as inadequate pigment dispersion and image density.

Innovation Solution

An oil-based inkjet ink formulation containing a pigment, an amide-based dispersant, and a non-aqueous solvent comprising a modified silicone oil with 2 or 3 silicon atoms and a petroleum-based hydrocarbon solvent, which improves pigment dispersion, reduces nozzle adhesion, and enhances image density while preventing show-through.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional oil-based inkjet inks are used, then the ink can be jetted from nozzles, but the ink exhibits poor discharge stability after a long idle period due to nozzle adhesion

Engineering Contradiction:
Improvedischarge stabilityVSAvoididle period
Core Design Contradiction:
ReliabilityVSDuration of action of stationary object

Solution Approach 1:

The patent changes the chemical parameters of the solvent system by using a specific mixture of silicone oil (with controlled viscosity and silicon atom count) and petroleum-based hydrocarbon solvent in defined ratios. This parameter optimization reduces nozzle adhesion during idle periods while maintaining discharge stability, directly resolving the contradiction between reliability and duration of action.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs a composite solvent system combining silicone oil and petroleum-based hydrocarbon solvent. This composite material leverages the low surface tension and nozzle-wetting properties of silicone oil alongside the volatility control of petroleum solvents, achieving both good discharge stability and reduced nozzle adhesion during extended idle periods.

Inventive Principle:
Principle #40Composite materials

2Reliability

If conventional oil-based inkjet inks are used, then the ink can dry on the recording medium, but the ink exhibits show-through in printed items

Engineering Contradiction:
Improveprint qualityVSAvoidshow-through
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent optimizes the viscosity and composition parameters of the petroleum-based hydrocarbon solvent component. By controlling these parameters within specific ranges, the ink formulation achieves better penetration control and drying characteristics that prevent show-through while maintaining high print quality and image density.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent modifies the local chemical composition of the ink near the recording medium interface by selecting specific petroleum-based hydrocarbon solvents with controlled volatility and solubility parameters. This local optimization ensures proper ink setting and penetration control at the paper interface, preventing show-through while maintaining overall print quality.

Inventive Principle:
Principle #3Local quality

3Quantity of substance

If conventional dispersants are used, then the pigment can be dispersed in the ink, but the ink exhibits inadequate image density

Engineering Contradiction:
Improveimage densityVSAvoidpigment dispersion
Core Design Contradiction:
Quantity of substanceVSStability of the object's composition

Solution Approach 1:

The patent changes the chemical parameters of the dispersant system by using amide-based dispersants with specific molecular structures and concentrations. This parameter optimization enhances pigment wetting and dispersion stability while increasing light absorption and image density, simultaneously improving both quantity of substance and compositional stability.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs amide-based dispersants as intermediary substances between the pigment particles and the solvent system. These dispersants provide optimal interfacial compatibility and adhesion, ensuring stable pigment dispersion throughout the ink while maximizing pigment utilization for high image density output.

Inventive Principle:
Principle #24Intermediary (Mediator)

4Speed

If volatile organic solvents are used, then the ink can dry quickly through evaporation, but the ink exhibits poor discharge stability due to volatility

Engineering Contradiction:
Improvedrying speedVSAvoiddischarge stability
Core Design Contradiction:
SpeedVSReliability

Solution Approach 1:

The patent changes the volatility parameters of the solvent system by selecting petroleum-based hydrocarbon solvents with controlled boiling points and vapor pressures. This parameter adjustment provides moderate evaporation rates that ensure quick drying while maintaining sufficient discharge stability, resolving the contradiction between speed and reliability.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses a composite solvent system where petroleum-based hydrocarbon solvents provide controlled volatility for adequate drying speed, while silicone oil components maintain low surface tension for stable nozzle discharge. This composite approach balances drying speed and discharge stability that cannot be achieved with single volatile organic solvents.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The ink exhibits excellent discharge stability after a long idle period and achieves high image density while preventing show-through in printed items by using a combination of amide-based dispersants and modified silicone oils with petroleum-based hydrocarbon solvents.

Implementation Method 1

an amide-based dispersant and a non-aqueous solvent, wherein the non-aqueous solvent contains a modified silicone oil having 2 or 3 silicon atoms in one molecule

Methodology Applied
Scientific EffectDispersion: Dispersion (of waves)

Implementation Method 2

a modified silicone oil having 2 or 3 silicon atoms in one molecule, and a petroleum-based hydrocarbon solvent

Methodology Applied
Scientific EffectSurface tension reduction: Surface Tension

Implementation Method 3

oil-based inks in which the main solvent is an organic solvent having either low volatility or no volatility... mainly dry as a result of penetration into the recording medium

Methodology Applied
Scientific EffectPenetration: Permeation

Data Source

PatentUS10865322B2Oil-based inkjet ink
Publication Date: 2020.12.15 RISO KAGAKU CORP
  • US10865322B2 patent drawing
  • US10865322B2 patent drawing

AI summary

An oil-based inkjet ink can be provided which exhibits excellent discharge stability even after a long idle period, and also yields high image density and prevents show-through in printed items. The oil-based inkjet ink contains a pigment, an amide-based dispersant and a non-aqueous solvent, wherein the non-aqueous solvent contains a modified silicone oil having 2 or 3 silicon atoms in one molecule, and a petroleum-based hydrocarbon solvent.