Oil-Based Sorel Cement for Water-Sensitive Wellbore Isolation

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Solution Overview

Problem

Existing wellbore servicing technologies face challenges with fluid loss and incompatibility with oleaginous fluids, particularly in formations sensitive to water, leading to ineffective zonal isolation and damage to subterranean formations.

Innovation Solution

A method using a composition comprising magnesium oxide, a soluble salt, an organophilic surfactant, and an oleaginous fluid, which sets to form a Sorel cement that is compatible with oleaginous fluids, preventing fluid loss and providing effective zonal isolation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If water-based Sorel cement compositions are used to plug lost circulation zones, then effective plugging and zonal isolation are achieved, but formations sensitive to water (containing swelling clay and shales) suffer damage and sloughing

Engineering Contradiction:
Improveplugging effectivenessVSAvoidformation damage
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent changes the fundamental parameter of the cement composition by replacing water-based formulations with oil-based Sorel cement compositions. This parameter change allows the cement to provide effective plugging functionality while eliminating the harmful water contact with sensitive formations, thereby resolving the contradiction between plugging effectiveness and formation protection

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite material system combining Sorel cement with oil-based fluids and compatible additives. This composite approach enables the cement to maintain its plugging and zonal isolation capabilities while the oil-based matrix prevents formation damage, simultaneously achieving both competing objectives

Inventive Principle:
Principle #40Composite materials

2Object-affected harmful factors

If oleaginous fluids are used in water-sensitive formations, then formation damage is prevented, but compatibility with Sorel cement compositions becomes problematic

Engineering Contradiction:
Improveformation damageVSAvoidcement compatibility
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent changes the base fluid parameter from water to oil, creating an oil-based Sorel cement composition. This parameter change fundamentally alters the chemical compatibility profile, allowing the use of oleaginous fluids in water-sensitive formations while maintaining cement functionality through careful formulation with compatible additives

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent develops a composite oil-based Sorel cement system that integrates Sorel cement particles with oil-based fluids and specialized additives. This composite structure achieves both formation protection and cement reliability by creating a chemically compatible system where oil replaces water as the continuous phase

Inventive Principle:
Principle #40Composite materials

3Loss of substance

If conventional plugging materials (walnut hulls, mica, cellophane) are used to prevent fluid loss, then fluid loss is reduced, but the materials cannot be removed and may dislodge causing resumed fluid loss

Engineering Contradiction:
Improvefluid lossVSAvoidplugging durability
Core Design Contradiction:
Loss of substanceVSReliability

Solution Approach 1:

The patent employs Sorel cement as a temporary, sacrificial plugging material that fulfills its function of preventing fluid loss during drilling operations and then dissolves away when no longer needed. This disposable approach allows effective fluid loss prevention during the critical drilling phase while eliminating the long-term complications of permanent plugging materials

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent implements a strategy where the Sorel cement plug is intentionally designed to be discarded (dissolved) after serving its purpose. The cement is placed to prevent fluid loss during drilling, then later removed by dissolution when the wellbore is ready for subsequent operations, achieving both effective temporary plugging and clean removal without formation damage

Inventive Principle:
Principle #34Discarding and recovering

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively prevents fluid loss and ensures strong zonal isolation, maintaining the integrity of subterranean formations by forming a rigid mass with appreciable compressive strength, suitable for use in challenging drilling conditions.

Implementation Method 1

a composition comprising a metal oxide, a soluble salt, a surfactant and an oleaginous fluid

Methodology Applied
Scientific EffectSurfactant action: Surfactant

Implementation Method 2

Sorel cement compositions typically comprise magnesium oxide and a chloride or phosphate salt and water which together form for example magnesium oxychloride

Methodology Applied
Scientific EffectHydration reaction: Mineral Hydration

Data Source

PatentUS7350575B1Methods of servicing a wellbore with compositions comprising Sorel cements and oil based fluids
Publication Date: 2008.04.01 HALLIBURTON ENERGY SERVICES INC
  • US7350575B1 patent drawing

AI summary

A method of servicing a wellbore in contact with a subterranean formation comprising placing in the wellbore a composition comprising a metal oxide, a soluble salt, a surfactant and an oleaginous fluid, and allowing the composition to set. A method of cementing a wellbore comprising placing a first composition comprising magnesium oxide, a chloride or phosphate salt, an organophilic surfactant and an oleaginous fluid into a wellbore, allowing the composition to set, placing a second cementitious composition into the wellbore, and allowing the second cementitious composition to set. A method of servicing a wellbore comprising placing in the wellbore a composition comprising magnesium oxide, magnesium chloride, an organophilic surfactant, water and an oleaginous fluid wherein the organophilic surfactant is present in an amount of from about 0.25% to about 5% base on the combined weight of the magnesium oxide and magnesium chloride, and the oleaginous fluid is present in a ratio of from about 95:5 cement:oleaginous fluid to about 50:50 cement:oleaginous fluid.