OLED Light-Emitting Layer Amine Compounds Low Voltage

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Solution Overview

Problem

Current organic light-emitting diodes (OLEDs) face challenges in achieving low driving voltages and long lifespan, despite advancements in host and dopant materials.

Innovation Solution

The use of specific amine compounds represented by Chemical Formulas A and B, combined with a host compound represented by Chemical Formula D, in the light-emitting layer of OLEDs, which includes a first and second electrode, to enhance energy transfer and efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional host and dopant materials are used in OLEDs, then the device can achieve basic light emission, but the driving voltage remains high and lifespan is limited

Engineering Contradiction:
ImprovelifespanVSAvoiddriving voltage
Core Design Contradiction:
ReliabilityVSUse of energy by moving object

Solution Approach 1:

The patent changes the chemical structure parameters of host and dopant materials by introducing specific substituents (fluorene, carbazole, dibenzofuran, dibenzothiophene groups) and adjusting molecular weight and energy gap values to achieve lower driving voltage and extended lifespan

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates composite luminescent materials by combining host materials with specific dopant materials in optimized ratios, where the host provides structural framework and the dopant provides luminescent centers with appropriate energy levels, achieving synergistic effects that reduce voltage and extend lifespan

Inventive Principle:
Principle #40Composite materials

2Illumination intensity

If a single luminescent material is used, then the device structure is simple, but color purity and light emission efficiency are reduced due to intermolecular actions

Engineering Contradiction:
Improvelight emission efficiencyVSAvoidmaterial system complexity
Core Design Contradiction:
Illumination intensityVSDevice complexity

Solution Approach 1:

The host material acts as an intermediary that prevents direct intermolecular interactions between dopant molecules, while facilitating energy transfer from the host to the dopant luminescent centers, thereby maintaining high color purity and light emission efficiency

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent assigns different functional properties to different components: the host provides structural framework and energy transfer capability, while the dopant provides localized luminescent centers with specific emission wavelengths, achieving high color purity through spatial separation of functions

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration results in OLEDs that operate at lower driving voltages and exhibit longer lifespan compared to conventional OLEDs, while also controlling color coordinates of the emitted light.

Implementation Method 1

when a dopant is smaller in energy band gap than a host accounting for the light-emitting layer, the addition of a small amount of the dopant to the host generates excitons from the light-emitting layer so that the excitons are transported to the dopant, emitting light at high efficiency

Methodology Applied
Scientific EffectEnergy transfer: Fluorescence

Implementation Method 2

Organic light-emitting diodes (OLEDs), based on self-luminescence

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS10468603B2Organic light-emitting diode having low driving voltage and long lifespan
Publication Date: 2019.11.05 SFC CO LTD
  • US10468603B2 patent drawing
  • US10468603B2 patent drawing
  • US10468603B2 patent drawing

AI summary

The present disclosure relates to an organic light-emitting diode having a low driving voltage and long lifespan and more particularly, to an organic light-emitting diode, comprising a first electrode, a second electrode facing the first electrode, and a light-emitting layer interposed therebetween, wherein the light-emitting layer contains at least one of the amine compounds represented by the following Chemical Formula A or Chemical Formula B, plus the compound represented by Chemical Formula D. The structures of Chemical Formulas A, B, and D are the same as in the specification.