OLED Antioxidant Layer for Oxidation Suppression

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Solution Overview

Problem

Current light-emitting devices, such as OLEDs, face challenges in maintaining luminescence efficiency and lifespan due to oxidation and defect density in the electron transport region, which affects the performance and longevity of the emitter layers, particularly when using quantum dots.

Innovation Solution

Incorporating an antioxidant in the emission layer or electron transport region and an acid generator, which can be activated by ultraviolet rays or heat, reduces oxidation and defect density, thereby enhancing luminescence efficiency and extending the device's lifespan by reducing trap sites in the inorganic electron transport layer.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Use of energy by moving object

If an electron transport region is formed in conventional OLEDs, then electron transport function is improved, but oxidation and defect density increase reducing luminescence efficiency

Engineering Contradiction:
Improveelectron transport functionVSAvoidluminescence efficiency
Core Design Contradiction:
Use of energy by moving objectVSReliability

Solution Approach 1:

An antioxidant layer is introduced as an intermediary between the electron transport region and the emission layer. This antioxidant layer mediates the interaction by preventing direct contact between electrons and the emission layer materials, thereby suppressing oxidation reactions while maintaining electron transport functionality through the designated electron transport region.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent converts the harmful oxidation effect into a beneficial protective mechanism by using antioxidants. The antioxidants are deliberately placed to undergo oxidation reactions themselves, thereby protecting the emission layer materials from oxidation. This transforms the harmful oxidative environment into a protective shield that extends device lifespan and maintains luminescence efficiency.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

2Illumination intensity

If quantum dots are used in emission layers, then luminescence characteristics are improved, but oxidation susceptibility increases reducing device lifespan

Engineering Contradiction:
Improveluminescence characteristicsVSAvoiddevice lifespan
Core Design Contradiction:
Illumination intensityVSDuration of action of stationary object

Solution Approach 1:

The antioxidant layer serves as a protective intermediary between the quantum dot emission layer and the oxidative environment. It specifically protects the quantum dots from oxidation by absorbing or neutralizing reactive oxygen species before they can reach and degrade the quantum dot materials, thereby preserving both luminescence characteristics and extending device lifespan.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The antioxidant layer creates a chemically inert environment for the quantum dot emission layer by scavenging oxygen and reactive species. This effectively establishes a protective atmosphere around the quantum dots, preventing oxidation reactions that would otherwise degrade the quantum dots and reduce device lifespan, while allowing the quantum dots to maintain their superior luminescence properties.

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of antioxidants and acid generators in the light-emitting device suppresses oxidation, improves luminescence efficiency, and extends the device's lifespan by reducing defect density and trap sites, resulting in a high-quality electronic apparatus with improved performance.

Implementation Method 1

an acid generator, which can be activated by ultraviolet rays or heat

Methodology Applied
Scientific EffectPhotolysis: Photodissociation

Implementation Method 2

an acid generator, which can be activated by ultraviolet rays or heat

Methodology Applied
Scientific EffectThermal decomposition: Thermolysis

Implementation Method 3

Incorporating an antioxidant in the emission layer or electron transport region... suppresses oxidation

Methodology Applied
Scientific EffectOxidation: Oxidation

Data Source

PatentUS20230284471A1Light-emitting device and electronic apparatus including the same
Publication Date: 2023.09.07 SAMSUNG DISPLAY CO LTD
  • US20230284471A1 patent drawing
  • US20230284471A1 patent drawing
  • US20230284471A1 patent drawing

AI summary

A light-emitting device including a substrate; a first electrode disposed on the substrate; a second electrode facing the first electrode; an interlayer disposed between the first electrode and the second electrode, wherein the interlayer includes an emission layer; and an antioxidant, wherein the first electrode is a cathode, and the second electrode is an anode.