OLED Auxiliary Layer Compounds for Hole Transport and Leakage Reduction

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Organic light-emitting devices face challenges in achieving low driving voltage, high efficiency, and long lifespan due to limitations in hole transport and electron transport layers.

Innovation Solution

Incorporating a first auxiliary layer with specific compounds represented by Formula 1 and Formula 201 or 202 between the hole transport region and the emission layer, which enhances hole transport capability and reduces leakage current, thereby improving efficiency and lifespan.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Power

If conventional hole transport and electron transport layers are used, then the device structure is simple, but the driving voltage is high and efficiency is low

Engineering Contradiction:
Improvedriving voltageVSAvoidlayer structure
Core Design Contradiction:
PowerVSDevice complexity

Solution Approach 1:

The patent divides the hole transport region into multiple sub-layers: a hole transport layer and a first auxiliary layer positioned between the hole transport layer and the emission layer. This segmentation allows each layer to be optimized for specific functions, with the first auxiliary layer containing compounds of Formula 1 that enhance hole transport capability and reduce leakage current, thereby reducing driving voltage without excessive structural complexity

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The first auxiliary layer acts as an intermediary layer between the hole transport layer and the emission layer. It mediates the transition of holes from the hole transport layer to the emission layer, improving hole transport efficiency and reducing leakage current. The compounds of Formula 1 in this intermediate layer have specific molecular structures with electron-donating groups that facilitate hole injection and transport

Inventive Principle:
Principle #24Intermediary (Mediator)

2Duration of action of stationary object

If conventional transport layers are used, then the manufacturing process is simple, but the device lifespan is short

Engineering Contradiction:
Improvedevice lifespanVSAvoidmanufacturing complexity
Core Design Contradiction:
Duration of action of stationary objectVSEase of manufacture

Solution Approach 1:

The patent applies local quality by using different compounds with specific properties in different regions. The first auxiliary layer contains compounds of Formula 1 with specific molecular structures (containing electron-donating groups like alkyl, alkoxy, or aryl groups) that are locally optimized for hole transport and leakage current reduction at the interface between the hole transport layer and emission layer, thereby extending device lifespan

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The first auxiliary layer uses composite material design by combining compounds of Formula 1 (with specific heteroatomic rings and electron-donating groups) with compounds of Formula 201 or 202. This composite approach creates synergistic effects that improve both device lifespan and manufacturing characteristics

Inventive Principle:
Principle #40Composite materials

3Productivity

If conventional transport layers are used, then the device structure is simple, but efficiency is low due to poor hole transport capability and high leakage current

Engineering Contradiction:
Improvedevice efficiencyVSAvoidlayer structure
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent changes the chemical and physical parameters of the hole transport region by introducing compounds of Formula 1 with specific molecular structures. These compounds have tailored parameters including molecular weight, glass transition temperature, HOMO/LUMO energy levels, and charge carrier mobility, which are optimized to enhance hole transport capability and reduce leakage current, thereby improving device efficiency

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The first auxiliary layer serves as an intermediary that improves the interface between the hole transport layer and emission layer. The compounds of Formula 1 in this layer have specific energy level alignments that facilitate efficient hole injection into the emission layer while blocking electrons, reducing leakage current and improving overall device efficiency

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The proposed solution results in an organic light-emitting device with a low driving voltage and extended lifespan by optimizing the hole transport characteristics and reducing leakage current through the use of the auxiliary layer compounds.

Implementation Method 1

Holes provided from the first electrode may move toward the emission layer through the hole transport region

Methodology Applied
Scientific EffectHole transport: Conduction (electrical)

Implementation Method 2

reduces leakage current through the use of the auxiliary layer compounds

Methodology Applied
Scientific EffectLeakage current reduction: Electrical Resistance

Implementation Method 3

Carriers, such as holes and electrons, may recombine in the emission layer to produce excitons. These excitons may transition from an excited state to a ground state, thus generating light

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS10490749B2Organic light emitting device
Publication Date: 2019.11.26 SAMSUNG DISPLAY CO LTD
  • US10490749B2 patent drawing
  • US10490749B2 patent drawing
  • US10490749B2 patent drawing

AI summary

An organic light-emitting device includes a first electrode and a second electrode facing the first electrode. An organic layer is between the first electrode and the second electrode. The organic layer includes an emission layer. A hole transport region is between the first electrode and the emission layer. A first auxiliary layer is between the hole transport region and the emission layer. The first auxiliary layer includes a first compound represented by Formula 1.