OLED Barrier Layer Work Function Optimization

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Solution Overview

Problem

Organic light emitting diode displays face challenges in light emission efficiency and lifespan due to limitations in electron injection and emission layer design, particularly requiring improvements in response speed, viewing angle, and contrast ratio compared to traditional LCDs.

Innovation Solution

The organic light emitting element incorporates a barrier layer with a higher work function than the second electrode, along with an electron injection layer and emission layer, optimized with specific materials and layer structures to control electron injection and emission efficiency, including a halogen dipole material and a thin barrier layer to enhance emission efficiency and extend lifespan.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If a conventional electron injection layer and electrode structure are used, then the device structure is simple, but the light emission efficiency and lifespan are insufficient

Engineering Contradiction:
Improvedevice structure simplicityVSAvoidlight emission efficiency
Core Design Contradiction:
Ease of manufactureVSProductivity

Solution Approach 1:

The electron injection layer is divided into two distinct sub-layers: a first electron injection sub-layer adjacent to the emission layer and a second electron injection sub-layer adjacent to the second electrode. This segmentation allows each sub-layer to be optimized for different functions, improving overall electron injection efficiency and light emission performance while maintaining structural clarity

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent employs composite material structures in multiple layers including the electron injection layer combining different materials with complementary properties, the emission layer using host-guest composite systems, and the electrode structure integrating low-work-function materials with barrier layers. These composite structures enhance electron injection efficiency and device stability, resolving the contradiction between structural simplicity and performance

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If the barrier layer work function is not optimized relative to the second electrode, then the manufacturing process is simple, but the electron injection efficiency and device lifespan are limited

Engineering Contradiction:
Improvemanufacturing process simplicityVSAvoiddevice lifespan
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent specifies that the barrier layer must have a work function greater than that of the second electrode by 0.1-1.0 eV. This precise parameter control optimizes the energy level alignment at the barrier layer/second electrode interface, facilitating efficient electron injection while preventing detrimental electron accumulation that would degrade the device. The controlled work function difference extends device lifespan without complicating the manufacturing process

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The barrier layer serves as an intermediary between the electron injection layer and the second electrode. By positioning this layer with specifically tuned work function properties, it mediates electron transport, creating favorable energy level alignment that enhances electron injection efficiency and device stability while maintaining manufacturing simplicity

Inventive Principle:
Principle #24Intermediary (Mediator)

3Device complexity

If electron injection and emission layer design are not optimized, then the device structure remains simple, but response speed and viewing angle performance are insufficient

Engineering Contradiction:
Improvedevice structure complexityVSAvoidresponse speed
Core Design Contradiction:
Device complexityVSSpeed

Solution Approach 1:

The patent applies local quality optimization by giving different regions of the electron injection layer distinct properties: the first sub-layer is optimized for electron transport to the emission layer, while the second sub-layer is optimized for electron supply from the electrode. The emission layer uses locally optimized host and dopant materials with specific energy levels. These localized optimizations improve response speed without requiring overall structural complexity

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The optimized electron injection structure enables dynamic electron transport that adapts to operational conditions. The dual sub-layer structure allows flexible electron flow modulation, improving response speed and enabling better viewing angle performance through enhanced carrier injection dynamics without increasing device structural complexity

Inventive Principle:
Principle #15Dynamics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration significantly improves light emission efficiency and extends the lifespan of the organic light emitting element while maintaining high contrast and response speed, addressing the limitations of existing OLED designs.

Implementation Method 1

a work function of the barrier layer is larger than a work function of the second electrode

Methodology Applied
Scientific EffectWork function difference:

Implementation Method 2

electrons, which are injected from one electrode, and holes, which are injected from another electrode

Methodology Applied
Scientific EffectElectron injection:

Implementation Method 3

the organic light emitting element forms excitons from combinations, which occur in an emission layer, of electrons, which are injected from one electrode, and holes, which are injected from another electrode, and the excitons emit energy such that light is emitted

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS10170723B2Organic light emitting element and organic light emitting display device including the same
Publication Date: 2019.01.01 SAMSUNG DISPLAY CO LTD
  • US10170723B2 patent drawing
  • US10170723B2 patent drawing
  • US10170723B2 patent drawing

AI summary

An organic light emitting element according to an exemplary embodiment of the present disclosure includes a first electrode, a second electrode, an emission layer between the first electrode and the second electrode, an electron injection layer between the second electrode and the emission layer, and a barrier layer between the electron injection layer and the second electrode, wherein a work function of the barrier layer is larger than a work function of the second electrode.