OLED Blue Emitter Using Composite Anthracene Derivatives

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Solution Overview

Problem

Conventional organic blue light-emitting devices using anthracene derivatives face limitations in color purity, efficiency, and lifetime.

Innovation Solution

Incorporating specific compounds represented by Formulas 1 and 2 into the organic layer of the OLED, which include a heteroaryl group and various substituents, to enhance the stability and performance of the device.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional anthracene derivatives are used in OLED, then the device structure is simple and manufacturing is easier, but color purity, efficiency, and lifetime are insufficient

Engineering Contradiction:
Improvedevice lifetimeVSAvoidorganic layer structure
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent employs composite organic layer structures combining multiple compounds (host material, guest material, and doping compounds) to achieve superior device performance. Specifically, the organic layer comprises a first organic compound and a second organic compound with different functional characteristics, creating a composite system that enhances color purity, efficiency, and lifetime while managing the increased structural complexity through systematic material selection

Inventive Principle:
Principle #40Composite materials

2Illumination intensity

If conventional anthracene derivatives are used in OLED, then the manufacturing process is simpler, but color purity and efficiency are limited

Engineering Contradiction:
Improvecolor purityVSAvoidorganic layer fabrication
Core Design Contradiction:
Illumination intensityVSEase of manufacture

Solution Approach 1:

The patent optimizes molecular parameters of the organic compounds including substituent groups (R1-R6), ring structures, and molecular weight ranges to achieve enhanced color purity. The specific structural parameters of the anthracene derivatives are carefully controlled to emit light in the 460-480nm wavelength range, while maintaining compatibility with conventional vacuum deposition and solution processing methods

Inventive Principle:
Principle #35Parameter changes

3Productivity

If the organic layer is stabilized with specific compounds, then color purity, efficiency, and lifetime improve, but driving voltage may increase

Engineering Contradiction:
Improvedevice efficiencyVSAvoiddriving voltage
Core Design Contradiction:
ProductivityVSUse of energy by moving object

Solution Approach 1:

The patent introduces compounds with specific local functional groups (such as electron-donating or electron-withdrawing substituents at specific positions on the anthracene core) to optimize charge transport and recombination zones. This localized functional differentiation enhances efficiency by concentrating luminescent activity in specific regions while maintaining overall low driving voltage through balanced charge injection from electrodes

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of these compounds improves the color purity, efficiency, and lifetime of the organic light-emitting device by stabilizing the organic layer, leading to higher performance without significant increases in driving voltage.

Implementation Method 1

An organic blue light-emitting device using a conventional existing anthracene derivative... When a voltage is applied between the anode and the cathode, holes injected from the anode move to the EML via the HTL, and electrons injected from the cathode move to the EML via the ETL. The holes and electrons recombine in the EML to generate excitons. When the excitons drop from an excited state to a ground state, light is emitted.

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS9276227B2Organic light-emitting device and flat panel display including the same
Publication Date: 2016.03.01 SAMSUNG DISPLAY CO LTD
  • US9276227B2 patent drawing
  • US9276227B2 patent drawing
  • US9276227B2 patent drawing

AI summary

An organic light-emitting device includes: a first electrode; a second electrode; and an organic layer interposed between the first electrode and the second electrode, wherein the organic layer includes a compound of Formula 1 and a compound of Formula 2; and a flat panel display device including the organic light-emitting device. Substituents in Formulae 1 and 2 are the same as described in the specification