Organic Light-Emitting Device Buffer Layers for Interface Stability

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Solution Overview

Problem

Conventional organic light-emitting devices experience device deterioration mainly at interfaces of organic layers, leading to suboptimal lifetime and emission efficiency, as well as higher driving voltages.

Innovation Solution

Incorporating a first buffer layer between the light-emitting layer and the hole transport layer, and a second buffer layer between the light-emitting layer and the electron transport layer, which are formed as simple or gradient layers to adjust the component mixture ratio and thickness, thereby facilitating charge balance and preventing rapid changes in hole and electron characteristics.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional organic light-emitting devices are operated without buffer layers, then the device structure is simpler, but device deterioration occurs at interfaces leading to reduced lifetime and emission efficiency

Engineering Contradiction:
Improvedevice lifetimeVSAvoidlayer structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

A buffer layer is introduced as an intermediary between the light-emitting layer and the hole transport layer. This buffer layer mediates the interface interactions, preventing direct contact between the light-emitting material and the hole transport material, thereby reducing interface deterioration and improving device lifetime and emission efficiency.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Power

If conventional organic light-emitting devices are operated without buffer layers, then the device structure is simpler, but driving voltage remains high

Engineering Contradiction:
Improvedriving voltageVSAvoidlayer structure complexity
Core Design Contradiction:
PowerVSDevice complexity

Solution Approach 1:

The buffer layer acts as a mediator that facilitates charge transfer between the light-emitting layer and the hole transport layer. By improving the charge balance and reducing charge accumulation at the interface, the buffer layer lowers the driving voltage required for device operation.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Productivity

If conventional organic light-emitting devices are operated without buffer layers, then the fabrication process is simpler, but emission efficiency is reduced

Engineering Contradiction:
Improveemission efficiencyVSAvoidlayer structure complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The buffer layer serves as an intermediary that optimizes the interface between the light-emitting layer and the hole transport layer. This improves charge balance and reduces non-radiative recombination at the interface, thereby enhancing the overall emission efficiency of the device.

Inventive Principle:
Principle #24Intermediary (Mediator)

4Stability of the object's composition

If conventional organic light-emitting devices are operated without buffer layers, then the device structure is simpler, but interface characteristics lead to rapid changes in hole and electron characteristics

Engineering Contradiction:
Improvecharge balance stabilityVSAvoidlayer structure complexity
Core Design Contradiction:
Stability of the object's compositionVSDevice complexity

Solution Approach 1:

The buffer layer acts as a stabilizing intermediary at the interface between the light-emitting layer and the hole transport layer. It prevents rapid changes in hole and electron characteristics by providing a transition zone that maintains charge balance stability during device operation.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The buffer layers enhance the emission efficiency and extend the lifetime of organic light-emitting devices while reducing driving voltages by improving interface characteristics and charge balance.

Implementation Method 1

The buffer layer serves to lower the driving voltage of the device and to enhance the lifetime of the device by adjusting an interface state of the light-emitting layer

Methodology Applied
Scientific EffectInterface state adjustment:

Implementation Method 2

Organic light-emitting devices are active emission display devices that emit light by recombination of electrons and holes in a thin layer (hereinafter, referred to as 'organic layer') formed of a fluorescent or phosphorescent organic compound when a current is applied to the organic layer

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Implementation Method 3

Materials that can be used to form a light-emitting layer in an organic light-emitting device are divided according to emission mechanisms into fluorescent materials using a singlet exciton

Methodology Applied
Scientific EffectFluorescence: Fluorescence

Implementation Method 4

phosphorescent materials using a triplet exciton

Methodology Applied
Scientific EffectPhosphorescence: Phosphorescence

Data Source

PatentUS7777408B2Organic light-emitting device
Publication Date: 2010.08.17 SAMSUNG ELECTRONICS CO LTD
  • US7777408B2 patent drawing
  • US7777408B2 patent drawing
  • US7777408B2 patent drawing

AI summary

Provided is an organic light-emitting device exhibiting lower driving voltages and improved lifetime characteristics and emission efficiency. The organic light-emitting device includes a cathode; an anode; and a light-emitting layer interposed between the cathode and the anode, wherein a buffer layer is disposed on at least one surface of the light-emitting layer.