OLED Buffer Layer Composition for Leakage Current Control

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Solution Overview

Problem

Existing organic light-emitting devices face challenges in preventing leakage currents and optimizing electron injection speeds, which can affect the device's lifespan and performance.

Innovation Solution

The introduction of a buffer layer in the organic light-emitting device, comprising a quinolinolato-based metal complex and a first compound with an electron transporting moiety, directly contacts the emission layer and helps regulate electron injection.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a buffer layer is introduced to reduce leakage currents, then device lifespan is improved, but device complexity increases

Engineering Contradiction:
Improvedevice lifespanVSAvoiddevice complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

A buffer layer comprising a quinolinolato-based metal complex and a first compound with electron transporting moiety is introduced between the emission layer and the second electrode. This intermediary layer regulates electron injection, reduces leakage currents, and extends device lifespan while maintaining a relatively simple single-layer structure.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The buffer layer uses a composite material system combining a quinolinolato-based metal complex (such as Alq3, Gaq3, Inq3, or Yq3) with a first compound containing electron transporting moieties (such as BPhen, Bpy, or phenanthroline derivatives). This composite approach optimizes both electron transport and leakage current reduction.

Inventive Principle:
Principle #40Composite materials

2Reliability

If the buffer layer composition is optimized to reduce leakage currents, then device reliability is improved, but manufacturing precision requirements increase

Engineering Contradiction:
Improveleakage current reductionVSAvoidmanufacturing precision
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The buffer layer composition is optimized by adjusting the weight ratio of the first compound to the quinolinolato-based metal complex within specific ranges (first compound: 1-50 wt%, quinolinolato-based metal complex: 50-99 wt%). This parameter optimization achieves effective leakage current reduction while maintaining ease of manufacturing through solution processing.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration effectively reduces leakage currents, prolongs the device's lifespan, and allows for adjustable electron injection speeds by varying the ratio of the first compound to the quinolinolato-based metal complex in the buffer layer.

Implementation Method 1

electrons provided from the second electrode may move toward the emission layer through the electron transport region

Methodology Applied
Scientific EffectElectron injection: Electron Beam

Implementation Method 2

a first compound and a quinolinolato-based metal complex, and the first compound is a compound including at least one electron transporting moiety

Methodology Applied
Scientific EffectElectron transport: Conduction (electrical)

Implementation Method 3

Carriers, such as holes and electrons, recombine in the emission layer to produce excitons. These excitons transit from an excited state to a ground state, thereby generating light

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS12295261B2Organic light-emitting device
Publication Date: 2025.05.06 SAMSUNG DISPLAY CO LTD
  • US12295261B2 patent drawing
  • US12295261B2 patent drawing
  • US12295261B2 patent drawing

AI summary

An organic light-emitting device including: a first electrode; a second electrode facing the first electrode; and an organic layer between the first electrode and the second electrode, wherein the organic layer includes an emission layer and a buffer layer between the emission layer and the second electrode, the buffer layer directly contacts the emission layer and includes a first compound and a quinolinolato-based metal complex, and the first compound is a compound including at least one electron transporting moiety.