OLED Capping Layer With Radical Scavenger for UV Stability

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Solution Overview

Problem

Organic light-emitting devices face issues with radical formation due to UV light exposure, leading to pixel shrinkage and emission region degradation, as existing technologies lack effective radical scavenging mechanisms.

Innovation Solution

Incorporating a capping layer with an amine-based compound and a radical scavenger in the organic light-emitting device structure, which reduces radical concentration and minimizes the impact of UV light on the emission regions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a conventional organic light-emitting device structure is used, then the device can emit light with good electrical characteristics, but radical formation occurs under UV light exposure leading to pixel shrinkage and emission region degradation

Engineering Contradiction:
Improvedevice stability under UV lightVSAvoidradical formation and pixel shrinkage
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent introduces a capping layer as an intermediary component between the second electrode and the external environment. This capping layer contains a radical scavenger that actively neutralizes radicals generated under UV light exposure, preventing them from reaching and damaging the emission layer. The capping layer thus serves as a protective mediator that blocks harmful radicals while allowing the device to maintain its light-emitting function.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent converts the harmful effect of UV light-induced radical formation into a beneficial protective mechanism. By incorporating a radical scavenger in the capping layer, the previously harmful radicals are now captured and neutralized, transforming the UV exposure scenario from damaging to protective. The radical scavenger effectively uses the presence of radicals as a trigger for its protective action, converting the harm into a benefit by preventing pixel shrinkage and emission region degradation.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

2Productivity

If the device operates under UV light exposure, then the device can function normally, but radical concentration increases causing emission region degradation

Engineering Contradiction:
Improvedevice operation under UV lightVSAvoidemission region integrity
Core Design Contradiction:
ProductivityVSLoss of substance

Solution Approach 1:

The patent implements preliminary protective action by pre-installing a radical scavenger in the capping layer before UV light exposure occurs. This radical scavenger is positioned in advance to intercept and neutralize radicals as soon as they are generated under UV light, preventing them from accumulating and causing damage to the emission layer. The protective mechanism is already in place and activated before any degradation can occur.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The capping layer with radical scavenger acts as an intermediary barrier between the UV light exposure and the emission layer. It selectively allows UV light to pass through for normal device operation while blocking and neutralizing the harmful radicals generated during UV exposure, thus protecting the emission region integrity without affecting device productivity.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The proposed solution effectively reduces radical formation and subsequent pixel shrinkage, maintaining the integrity and performance of the organic light-emitting device emission regions under UV light exposure.

Implementation Method 1

a capping layer on the second electrode, wherein the capping layer includes an amine-based compound represented by Formula 1 and a radical scavenger

Methodology Applied
Scientific EffectRadical scavenging: Absorption (physical)

Data Source

PatentUS11744148B2Organic light-emitting device and light-emitting apparatus including the same
Publication Date: 2023.08.29 SAMSUNG DISPLAY CO LTD
  • US11744148B2 patent drawing
  • US11744148B2 patent drawing
  • US11744148B2 patent drawing

AI summary

Provided are an organic light-emitting device including a capping layer including an amine-based compound represented by a set or predetermined formula and a radical scavenger, and a light-emitting apparatus including the organic light-emitting device. The organic light-emitting device includes: a first electrode; a second electrode facing the first electrode; an organic layer between the first electrode and the second electrode and including an emission layer a capping layer on the second electrode, wherein the capping layer includes the amine-based compound.