OLED Coating Compound for Stable Charge Transfer and Low-Voltage Driving

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Solution Overview

Problem

Existing organic light emitting devices face challenges with materials that lack thermal stability, efficient charge transfer, chemical stability, and optimal band gap for low voltage driving, leading to inefficiencies and reduced device lifetime.

Innovation Solution

A compound represented by Chemical Formula 2, which forms the basis of a coating composition, enables improved thermal and photostability, enhances charge mobility, and allows for low-temperature curing, facilitating efficient solvent use and large-area device manufacturing.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If NPB is used as hole transfer layer material, then the device can be manufactured with conventional materials, but the glass transition temperature is 100°C or lower making it difficult to use in high current devices

Engineering Contradiction:
Improveglass transition temperatureVSAvoidthermal stability
Core Design Contradiction:
TemperatureVSReliability

Solution Approach 1:

The patent modifies the chemical structure of hole transfer materials by introducing specific molecular configurations and substituents to elevate the glass transition temperature above 100°C, thereby achieving the required thermal stability for high current devices while maintaining hole transfer functionality

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent develops composite hole transfer materials combining multiple organic compounds with complementary properties, where the composite structure achieves both high glass transition temperature and effective charge transport, resolving the contradiction between thermal stability and material performance

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If PEDOT:PSS is used as hole transfer material, then the device can be manufactured using solution coating method, but the LUMO energy level is lower than light emitting layer material causing efficiency and lifetime problems

Engineering Contradiction:
Improvesolution coating capabilityVSAvoidenergy level compatibility
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent designs hole transfer materials with specifically tuned HOMO and LUMO energy levels that are higher than those of light emitting layer materials, ensuring proper energy level alignment for efficient charge transfer while maintaining solution processability through molecular structure optimization

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces intermediary hole transfer materials that act as energy level buffers between the electrode and light emitting layer, mediating charge transfer while preventing electron leakage and maintaining compatibility with solution coating manufacturing methods

Inventive Principle:
Principle #24Intermediary (Mediator)

3Productivity

If materials with high charge mobility are used to maximize exciton formation, then the device efficiency improves, but the material deformation caused by moisture or oxygen increases

Engineering Contradiction:
Improveexciton formation efficiencyVSAvoidchemical stability
Core Design Contradiction:
ProductivityVSStability of the object's composition

Solution Approach 1:

The patent develops composite material systems where hydrophobic components provide chemical stability against moisture and oxygen, while charge transport components maintain high mobility, achieving both exciton formation efficiency and long-term device stability through synergistic material combination

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent applies local quality protection by introducing moisture-resistant and oxygen-resistant functional groups at specific locations within the material structure, particularly at interfaces and charge transport pathways, to protect against environmental degradation while maintaining overall charge mobility

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The compound improves device efficiency, reduces driving voltage, and extends the lifetime of organic light emitting devices by ensuring stable exciton formation and interface properties.

Implementation Method 1

An organic material layer formed using a compound according to one embodiment of the present specification has excellent thermal and photostability after being cured through heat and light

Methodology Applied
Scientific EffectCuring:

Implementation Method 2

The holes and the electrons injected to the organic material layer recombine to form excitons, and light emits when these excitons fall back to the ground state

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentEP3686186B1Compound, coating composition comprising same, and organic light emitting diode
Publication Date: 2026.03.04 LG CHEM LTD
  • EP3686186B1 patent drawingFigure 1
  • EP3686186B1 patent drawing
  • EP3686186B1 patent drawing

AI summary

The present specification relates to a compound, a coating composition including the same, and an organic light emitting device.