OLED Coating Compound for Stable Solution-Processed Thin Films

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Solution Overview

Problem

Existing organic light emitting devices manufactured via deposition processes suffer from material loss and inefficiencies, requiring materials that can form stable solutions, ensure uniform thin film formation, and maintain solvent resistance and high efficiency during the solution process.

Innovation Solution

A compound represented by Chemical Formula 1, with asymmetric substituents and a vinyl group for enhanced solubility and curing, is used in a coating composition to form organic material layers, allowing for efficient manufacturing via a solution process.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If a deposition process is used to manufacture organic light emitting devices, then the device can be manufactured with existing materials, but material loss occurs and production efficiency is reduced

Engineering Contradiction:
Improveproduction efficiencyVSAvoidmaterial loss
Core Design Contradiction:
ProductivityVSLoss of substance

Solution Approach 1:

The patent replaces the deposition process (physical/mechanical method) with a solution process (chemical method). The compound is dissolved in a solvent to form a coating composition that can be applied via solution-based techniques, eliminating material loss associated with deposition and improving production efficiency.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent changes the physical state and solubility parameters of the compound by introducing specific molecular structures (asymmetric substituents, vinyl groups) that enable the material to form stable solutions. This parameter change allows transition from deposition to solution processing.

Inventive Principle:
Principle #35Parameter changes

2Stability of the object's composition

If commercialized materials for deposition process are used, then good crystallinity is achieved, but the materials do not dissolve well in solution and form stable solutions

Engineering Contradiction:
Improvesolution stabilityVSAvoidsolubility
Core Design Contradiction:
Stability of the object's compositionVSEase of manufacture

Solution Approach 1:

The patent introduces asymmetric substituents into the molecular structure of the compound. This asymmetry disrupts the high crystallinity that prevents solubility, while maintaining the core functional properties needed for device performance, enabling the material to dissolve and form stable solutions.

Inventive Principle:
Principle #4Asymmetry

Solution Approach 2:

The patent modifies molecular parameters such as symmetry, polarity, and intermolecular interaction by introducing specific functional groups and substituents. These parameter changes reduce crystallinity and enhance solubility while preserving solution stability through proper molecular design.

Inventive Principle:
Principle #35Parameter changes

3Loss of substance

If a solution process is used to form thin films, then material loss is reduced, but holes or aggregation phenomena may occur in the thin film

Engineering Contradiction:
Improvematerial lossVSAvoidthin film uniformity
Core Design Contradiction:
Loss of substanceVSManufacturing precision

Solution Approach 1:

The patent optimizes solution parameters including viscosity, concentration, and drying characteristics by modifying the compound's molecular structure. The vinyl groups and asymmetric substituents control solution flow and evaporation rates, enabling formation of uniform thin films without holes or aggregation.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces deposition-based film formation with solution-based coating methods. The coating composition is applied as a liquid solution that self-assembles into uniform films during drying, eliminating the material loss of deposition while achieving good film uniformity through proper solution formulation.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

4Ease of manufacture

If new organic materials are developed for solution process, then coatability and solution stability improve, but solvent resistance and service life characteristics need to be maintained

Engineering Contradiction:
ImprovecoatabilityVSAvoidsolvent resistance
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent creates a composite molecular structure combining the core functional units needed for device performance with asymmetric substituents and vinyl groups for solubility. This composite structure maintains the functional properties for solvent resistance while adding the coatability features needed for solution processing.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The compound enables large-area devices with low driving voltage, high light emission efficiency, and improved service life characteristics.

Implementation Method 1

the material used in the organic light emitting device needs to be able to form a storable homogenous solution

Methodology Applied
Scientific EffectSolubility: Solvation

Implementation Method 2

a material used for a solution process needs to be excellent in coatability such that during the formation of a thin film, a thin film having a uniform thickness may be formed without the occurrence of holes or an aggregation phenomenon

Methodology Applied
Scientific EffectCoating: Coatings

Implementation Method 3

An organic light emission phenomenon is one of the examples of converting an electric current into visible rays through an internal process of a specific organic molecule. When an organic material layer is disposed between an anode and a cathode and an electric current is applied between the two electrodes, electrons and holes are injected into the organic material layer from the cathode and the anode, respectively. The electrons and the holes which are injected into the organic material layer are recombined to form an exciton, and the exciton falls down again to the ground state to emit light.

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentEP4253389B1Compound, coating composition comprising same, organic light-emitting device using same, and manufacturing method therefor
Publication Date: 2025.11.26 LG CHEM LTD
  • EP4253389B1 patent drawingFigure 1
  • EP4253389B1 patent drawingFigure 2
  • EP4253389B1 patent drawingFigure 3

AI summary

The present specification relates to a compound represented by Chemical Formula 1, a coating composition including the compound represented by Chemical Formula 1, an organic light emitting device using the same, and a method of manufacturing the same.