OLED Emission Layer Composite Host Materials

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Solution Overview

Problem

Existing organic light emitting devices face limitations in achieving balanced hole and electron transport properties, leading to suboptimal efficiency and lifespan, particularly when using single host materials in the emission layer.

Innovation Solution

Incorporating a combination of hole transport host material, electron transport host material, and bipolar host material in the emission layer, along with dopant materials, to enhance both hole and electron transport properties and improve device efficiency and lifespan.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Device complexity

If a single host material is used in the emission layer, then the device structure is simple, but the charge transport balance and device lifespan are insufficient

Engineering Contradiction:
Improveemission layer structureVSAvoiddevice lifespan
Core Design Contradiction:
Device complexityVSReliability

Solution Approach 1:

The emission layer employs a composite host material system comprising three distinct components: hole transport host material (e.g., TCTA), electron transport host material (e.g., Alq3), and bipolar host material (e.g., BCP). This composite structure enables simultaneous optimization of hole injection, electron injection, and charge transport balance, achieving superior device lifespan and efficiency compared to single host material systems.

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If a single host material is used in the emission layer, then the manufacturing process is simple, but the charge transport balance is poor

Engineering Contradiction:
Improveemission layer fabricationVSAvoidcharge transport balance
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

Each host material component is strategically selected to provide specific local functions: TCTA primarily facilitates hole transport, Alq3 primarily facilitates electron transport, and BCP provides bipolar characteristics. This localized functional assignment within the emission layer achieves excellent charge transport balance while maintaining compatibility with conventional vacuum deposition manufacturing processes.

Inventive Principle:
Principle #3Local quality

3Productivity

If multiple host materials are used in the emission layer, then the charge transport balance and efficiency are improved, but the device complexity increases

Engineering Contradiction:
Improvedevice efficiencyVSAvoidemission layer composition
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The emission layer design achieves multi-functionality through the synergistic combination of three host materials that collectively provide hole injection, electron injection, and charge transport functions. This universal approach enables a single emission layer to perform multiple critical functions simultaneously, improving device efficiency without requiring separate functional layers.

Inventive Principle:
Principle #6Universality (Multi-functionality)

4Duration of action of stationary object

If multiple host materials are used in the emission layer, then the device lifespan is extended, but the material selection and fabrication complexity increase

Engineering Contradiction:
Improvedevice lifespanVSAvoidemission layer material system
Core Design Contradiction:
Duration of action of stationary objectVSDevice complexity

Solution Approach 1:

The emission layer utilizes parameter optimization by carefully selecting the molecular structures and concentrations of the three host materials. By adjusting the HOMO/LUMO energy levels, mobility ratios, and concentration ratios of TCTA, Alq3, and BCP, the system achieves optimal charge transport balance and extended device lifespan while maintaining manageable fabrication complexity through conventional vacuum deposition techniques.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of multiple host materials in the emission layer significantly improves the efficiency and lifespan of organic light emitting devices by balancing charge transport and emission properties, outperforming devices using single or dual host materials.

Implementation Method 1

the hole transport layer, the emission layer, and the electron transport layer are organic thin films formed using organic compounds

Methodology Applied
Scientific EffectCharge transport: Conduction (electrical)

Implementation Method 2

An organic light emitting device is a self-luminescent type device and has wide viewing angles and good contrast

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS9876180B2Organic light emitting device and display device having the same
Publication Date: 2018.01.23 SAMSUNG DISPLAY CO LTD
  • US9876180B2 patent drawing
  • US9876180B2 patent drawing
  • US9876180B2 patent drawing

AI summary

An organic light emitting device and a display device including the same, the organic light emitting device including a first electrode; a hole controlling layer on the first electrode; an emission layer on the hole controlling layer; an electron controlling layer on the emission layer; and a second electrode on the electron controlling layer, wherein the emission layer includes a hole transport host material, an electron transport host material, a bipolar host material, and at least one dopant material.