Organic Light Emitting Diode Compound for Charge Transport and Stability

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Solution Overview

Problem

Current organic optoelectronic devices, such as organic light emitting diodes, face challenges in achieving excellent lifespan, efficiency, and stability due to inefficient electron mobility and interactions between molecules, leading to reduced luminous efficiency and increased risk of device degradation from Joule heating.

Innovation Solution

A compound with specific chemical structures, represented by various chemical formulae, is introduced that can act as both a hole injection/transport material and an electron injection/transport material, providing improved electrochemical and thermal stability, and serving as a host for dopants in organic optoelectronic devices, enhancing charge transport and reducing molecular interactions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional organic light emitting materials are used, then the device can emit light, but the lifespan and stability are reduced due to inefficient electron mobility and molecular interactions

Engineering Contradiction:
Improvedevice lifespan and stabilityVSAvoidelectron mobility efficiency
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent modifies the molecular structure of organic compounds by introducing specific functional groups (carbazole, dibenzofuran, dibenzothiophene) and adjusting substituents to optimize electron mobility and reduce molecular interactions, thereby improving device lifespan and stability while maintaining high productivity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent develops composite organic compounds combining multiple functional moieties (hole injection, electron transport, light emission) into single molecular structures, achieving synergistic effects that simultaneously improve reliability and electron mobility efficiency

Inventive Principle:
Principle #40Composite materials

2Use of energy by moving object

If high current is applied to achieve high luminous efficiency, then more light is emitted, but Joule heating increases causing device degradation

Engineering Contradiction:
Improveluminous efficiencyVSAvoidJoule heating and device degradation
Core Design Contradiction:
Use of energy by moving objectVSObject-affected harmful factors

Solution Approach 1:

The patent designs organic compounds with high thermal stability and efficient charge transport capabilities, converting the harmful Joule heating effect into beneficial thermal management through enhanced heat dissipation pathways provided by the molecular structure, allowing high current operation without degradation

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The patent optimizes the HOMO-LUMO energy levels and molecular packing arrangements to reduce resistive heating while maintaining high electron mobility, thereby achieving high luminous efficiency with minimal Joule heating and improved device stability

Inventive Principle:
Principle #35Parameter changes

3Reliability

If multiple separate materials are used for hole injection, electron transport, and light emission, then each function can be optimized, but the device complexity increases

Engineering Contradiction:
Improvefunctional optimizationVSAvoidmaterial layer structure
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent designs multifunctional organic compounds that simultaneously provide hole injection, electron transport, and light emission capabilities within single molecular structures, eliminating the need for multiple separate functional layers and simplifying device architecture while maintaining optimized performance

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The patent merges multiple functional moieties (carbazole for hole transport, dibenzofuran/dibenzothiophene for electron transport, and aromatic substituents for light emission) into integrated molecular structures, combining separate functions into unified materials that reduce device complexity

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The compound improves the lifespan and efficiency of organic optoelectronic devices by promoting efficient charge transport, reducing molecular interactions, and enhancing thermal stability, thereby lowering driving voltage and increasing luminous efficiency.

Implementation Method 1

A first organic optoelectronic device is an electronic device driven as follows: excitons are generated in an organic material layer by photons from an external light source; the excitons are separated into electrons and holes; and the electrons and holes are transferred to different electrodes as a current source (voltage source)

Methodology Applied
Scientific EffectHole injection and transport:

Implementation Method 2

A second organic optoelectronic device is an electronic device driven as follows: a voltage or a current is applied to at least two electrodes to inject holes and/or electrons into an organic material semiconductor positioned at an interface of the electrodes, and the device is driven by the injected electrons and holes

Methodology Applied
Scientific EffectElectron injection and transport:

Implementation Method 3

In general, organic light emission refers to conversion of electrical energy into photo-energy. Such an organic light emitting diode converts electrical energy into light by applying current to an organic light emitting material

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Implementation Method 4

Such a phosphorescent material emits lights by transporting the electrons from a ground state to an exited state, non-radiance transiting of a singlet exciton to a triplet exciton through intersystem crossing, and transiting a triplet exciton to a ground state to emit light

Methodology Applied
Scientific EffectPhosphorescence: Phosphorescence

Implementation Method 5

an organic optoelectronic device having excellent life-span, efficiency, electrochemical stability, and thermal stability

Methodology Applied
Scientific EffectJoule heating: Joule Heating

Data Source

PatentUS10333081B2Compound for organic optoelectronic device, organic light emitting diode including the same and display including the organic light emitting diode
Publication Date: 2019.06.25 SAMSUNG SDI CO LTD
  • US10333081B2 patent drawing
  • US10333081B2 patent drawing
  • US10333081B2 patent drawing

AI summary

A compound for an organic optoelectronic device, an organic light emitting diode including the same, and a display device including the organic light emitting diode are disclosed and the compound for an organic optoelectronic device represented by a combination of the following Chemical Formulae 1 and 2 provides an organic light emitting diode having life-span characteristics due to excellent electrochemical and thermal stability, and high luminous efficiency at a low driving voltage.