Organic Compound for OLED Efficiency and Stability

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Solution Overview

Problem

Organic electric elements face challenges with low efficiency, short lifespan, and color purity issues due to charge imbalance and material instability, particularly in the hole transport layer, and require materials that can withstand Joule heating and deposition processes.

Innovation Solution

A compound represented by a specific formula is used in the organic electric element, optimizing energy levels and T1 values across layers to enhance luminous efficiency, reduce driving voltage, and improve heat resistance and color purity, acting as a host or dopant in various layers.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a hole transport layer material with low HOMO value is used, then charge transport is improved, but T1 value decreases causing exciton transfer to the hole transport layer, resulting in reduced color purity and efficiency

Engineering Contradiction:
Improvecharge transportVSAvoidT1 value
Core Design Contradiction:
ReliabilityVSUse of energy by moving object

Solution Approach 1:

An emission-auxiliary layer is introduced as an intermediary between the hole transport layer and the light emitting layer. This layer has a HOMO level positioned between the HOMO energy levels of the hole transport layer and the light emitting layer, preventing exciton transfer to the hole transport layer while maintaining charge transport functionality. The emission-auxiliary layer acts as a buffer that resolves the contradiction between charge transport requirements and T1 value maintenance.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Productivity

If efficiency is increased, then driving voltage is lowered and life span increases, but material stability and charge balance become more critical

Engineering Contradiction:
Improveluminous efficiencyVSAvoidmaterial stability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The invention optimizes multiple parameters simultaneously: the emission-auxiliary layer is designed with specific HOMO level (between hole transport layer and light emitting layer HOMO levels), specific T1 value (higher than hole transport layer), and appropriate thickness (1-100 nm). These parameter optimizations work together to achieve high efficiency while maintaining material stability and preventing degradation during operation.

Inventive Principle:
Principle #35Parameter changes

3Ease of manufacture

If a hole injection layer material with low glass transition temperature is used, then ease of deposition is improved, but film uniformity collapses during operation, shortening life span

Engineering Contradiction:
Improvedeposition processVSAvoidlife span
Core Design Contradiction:
Ease of manufactureVSDuration of action of stationary object

Solution Approach 1:

The hole injection layer material is selected or designed with glass transition temperature above 100°C, which maintains film uniformity and structural integrity during element operation. This temperature parameter optimization prevents film collapse while still allowing for effective deposition processes, thereby extending the element's operational life span.

Inventive Principle:
Principle #35Parameter changes

4Reliability

If metal oxides penetrate from anode electrode into organic layer, then electrical contact is improved, but material stability decreases and life span is shortened

Engineering Contradiction:
Improveelectrical contactVSAvoidmaterial stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The hole injection layer serves as an intermediary barrier between the anode electrode and the organic layers. It provides sufficient electrical contact for device operation while preventing penetration and diffusion of metal oxides from the anode into the organic layers, thereby maintaining material stability and extending device life span.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The compound significantly improves the organic electric element's luminous efficiency, lifespan, and color purity while maintaining low driving voltage and heat resistance, addressing the material stability and efficiency concerns.

Implementation Method 1

An organic light emitting phenomenon refers to a phenomenon in which electric energy is converted into light energy of an organic material

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Implementation Method 2

the crystallization of an organic material due to Joule heating generated during operation is reduced

Methodology Applied
Scientific EffectJoule heating: Joule Heating

Implementation Method 3

In general, deposition is a main method of forming an OLED

Methodology Applied
Scientific EffectDeposition: Deposition (physical)

Data Source

PatentUS9515269B2Compound for organic electric element, organic electric element comprising the same and electronic device thereof
Publication Date: 2016.12.06 DUK SAN NEOLUX
  • US9515269B2 patent drawing
  • US9515269B2 patent drawing
  • US9515269B2 patent drawing

AI summary

The present invention provides a novel compound capable of improving light emitting efficiency, stability, and lifespan of the element, an organic element using the same, and an electric device for the same.