OLED Organic Compound Composition for Faster Hole Injection

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Solution Overview

Problem

The performance of organic light emitting diodes (OLEDs) is heavily influenced by the organic materials between electrodes, and there is a need for improved compounds and compositions that enhance hole injection, reduce driving voltage, and improve heat resistance and luminous efficiency.

Innovation Solution

A compound represented by Chemical Formula 1, which includes a fused dibenzosilole and benzofuran (or benzothiophene) skeleton with an amine group substitution, and a composition comprising a first and second compound, where the second compound extends the LUMO energy band, enhancing hole and electron balance, thereby improving luminous efficiency and lifespan.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Speed

If conventional organic materials are used in OLEDs, then device structure is simple, but hole injection is slow and driving voltage is high

Engineering Contradiction:
Improvehole injection speedVSAvoiddriving voltage
Core Design Contradiction:
SpeedVSPower

Solution Approach 1:

The patent modifies the molecular structure of organic compounds by introducing specific functional groups (amine groups, dibenzosilole skeletons, benzofuran/benzothiophene combinations) to change electronic parameters such as HOMO/LUMO energy levels and charge mobility, thereby improving hole injection speed and reducing driving voltage

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite organic materials combining multiple functional moieties (dibenzosilole core, benzofuran/benzothiophene units, amine substituents) within single molecules or in material combinations to achieve synergistic effects that enhance both hole injection and reduce operating voltage

Inventive Principle:
Principle #40Composite materials

2Temperature

If conventional organic materials are used in OLEDs, then manufacturing is straightforward, but thermal stability is poor

Engineering Contradiction:
Improvethermal stabilityVSAvoidmaterial synthesis complexity
Core Design Contradiction:
TemperatureVSEase of manufacture

Solution Approach 1:

The patent introduces specific rigid structural units (dibenzosilole skeleton, fused ring systems) at key positions within the molecular structure to locally enhance thermal stability without requiring complete redesign of the entire molecular architecture, maintaining relative manufacturing feasibility

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent performs preliminary molecular design incorporating thermally stable structural motifs (silole rings, fused aromatic systems) into the core framework before synthesis, preventing thermal degradation issues from arising during device operation

Inventive Principle:
Principle #10Preliminary action

3Productivity

If conventional organic materials are used in OLEDs, then device structure is simple, but luminous efficiency is low

Engineering Contradiction:
Improveluminous efficiencyVSAvoidcompound structure complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent optimizes photophysical parameters of organic compounds by adjusting molecular structure (introducing dibenzosilole-benzofuran/benzothiophene frameworks with amine groups) to improve radiative recombination efficiency and light emission properties, thereby enhancing luminous efficiency

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent utilizes established successful structural motifs from high-performance OLED materials (dibenzosilole core, aromatic heterocycles) and combines them in novel configurations, leveraging proven design principles to achieve high luminous efficiency

Inventive Principle:
Principle #26Copying

Data Source

PatentUS12492216B2Compound for organic optoelectronic device, composition for organic optoelectronic device, organic optoelectronic device and display device
Publication Date: 2025.12.09 SAMSUNG SDI CO LTD
  • US12492216B2 patent drawing
  • US12492216B2 patent drawing
  • US12492216B2 patent drawing

AI summary

A compound for an organic optoelectronic device, a composition for an organic optoelectronic device including the same, an organic optoelectronic device, and a display device, the compound being represented by Chemical Formula 1: