Organic Electroluminescent Compound for Thermal Stability and Low Voltage

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Solution Overview

Problem

Conventional luminescent materials used in organic electroluminescent devices have low glass transition temperatures and poor thermal stability, leading to unsatisfactory lifespan performance.

Innovation Solution

A novel organic compound with a structure featuring two electron-withdrawing groups linked by a m,m-biphenylene linker, providing excellent electron transport capability, thermal stability, and light emitting characteristics, is integrated into organic electroluminescent devices as a phosphorescent host material or electron transporting material.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional luminescent materials are used in organic electroluminescent devices, then the devices can achieve light emission functionality, but the devices exhibit poor thermal stability and short lifespan

Engineering Contradiction:
ImprovelifespanVSAvoidthermal stability
Core Design Contradiction:
ReliabilityVSTemperature

Solution Approach 1:

The patent modifies the molecular structure of luminescent materials by introducing electron-withdrawing groups (such as pyrimidine and triazine rings) and adjusting substituent patterns to raise the glass transition temperature from typically low values to above 100°C, thereby improving thermal stability and device lifespan while maintaining luminescent properties

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent develops composite organic materials combining electron-withdrawing heterocyclic groups with electron-donating groups or aromatic hydrocarbon groups, creating molecules that simultaneously achieve high thermal stability (Tg > 100°C), good electron transport capability, and effective luminescence, resolving the contradiction between thermal stability and luminescent functionality

Inventive Principle:
Principle #40Composite materials

2Productivity

If conventional luminescent materials are used, then the devices can operate, but the driving voltage remains high and current efficiency is low

Engineering Contradiction:
Improvecurrent efficiencyVSAvoiddriving voltage
Core Design Contradiction:
ProductivityVSUse of energy by stationary object

Solution Approach 1:

The patent optimizes molecular parameters including HOMO-LUMO energy levels, electron affinity, and molecular packing characteristics by adjusting substituent types and positions, achieving materials that reduce driving voltage while enhancing current efficiency through improved charge transport and exciton management

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent designs luminescent materials that simultaneously perform multiple functions: they act as electron transport materials, host materials for phosphorescent dopants, and luminescent emitters themselves, thereby improving current efficiency and reducing driving voltage through multifunctional operation

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The compound enhances the devices' thermal stability, electron transport efficiency, and lifespan, while reducing driving voltage and improving current efficiency, resulting in improved performance and durability.

Implementation Method 1

the compound having excellent electron transport capability

Methodology Applied
Scientific EffectElectron transport: Conduction (electrical)

Implementation Method 2

light emission occurs when the excitons fall to a ground state

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Implementation Method 3

the compound enhances the devices' thermal stability

Methodology Applied
Scientific EffectThermal stability: Thermal Insulation

Data Source

PatentUS11917910B2Organic compound and organic electroluminescent device using the same
Publication Date: 2024.02.27 SOLUS ADVANCED MATERIALS CO LTD
  • US11917910B2 patent drawing
  • US11917910B2 patent drawing
  • US11917910B2 patent drawing

AI summary

The present invention relates to a novel organic compound and an organic electroluminescent device using the same, and more particularly, to a novel compound having excellent electron transport capability and light emitting capability, and an organic electroluminescent device improved in terms of luminous efficiency, driving voltage, lifespan, etc. by including the novel compound in one or more organic layers.