OLED Semiconductor Compounds for Thermal and Voltage Stability

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Solution Overview

Problem

Existing organic light-emitting diodes (OLEDs) face challenges in thermal stability, LUMO energy level, and environmental impact of compounds used in the organic semiconductor layer, which affect efficiency and operating voltage stability.

Innovation Solution

Development of compounds of Formula (I) with specific structural features, including fluorinated and cyano groups, to enhance thermal stability and LUMO energy level, thereby improving operating voltage and stability over time.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If conventional organic compounds are used in the semiconductor layer, then device structure is simple, but thermal stability and LUMO energy level are insufficient

Engineering Contradiction:
Improvethermal stabilityVSAvoidcompound structure complexity
Core Design Contradiction:
Stability of the object's compositionVSDevice complexity

Solution Approach 1:

The patent modifies the molecular parameters of organic compounds by introducing fluorinated groups and cyano groups at specific positions. These parameter changes directly enhance thermal stability and adjust LUMO energy levels without fundamentally changing the device structure, resolving the contradiction between stability improvement and structural complexity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates composite organic compounds combining electron-withdrawing fluorinated groups, cyano groups, and electron-donating aromatic rings. This composite molecular structure achieves synergistic effects that improve thermal stability and tune energy levels while maintaining reasonable structural complexity for OLED fabrication

Inventive Principle:
Principle #40Composite materials

2Reliability

If conventional compounds are used, then manufacturing process is simple, but operating voltage stability over time deteriorates

Engineering Contradiction:
Improveoperating voltage stabilityVSAvoidmanufacturing complexity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

By changing molecular parameters through fluorination and cyano group introduction, the patent improves operating voltage stability. The modified compounds maintain compatibility with existing OLED manufacturing processes, balancing reliability improvement with ease of manufacture

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses small-molecule organic compounds that can be deposited as thin films in OLEDs. These molecules are designed to provide long-term operational stability without requiring complex manufacturing infrastructure, achieving reliable performance through molecular design rather than manufacturing complexity

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Productivity

If traditional organic compounds are used, then device structure is simple, but efficiency and LUMO energy level are insufficient

Engineering Contradiction:
Improvedevice efficiencyVSAvoidmolecular structure complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent optimizes molecular parameters by introducing fluorinated groups and cyano groups that enhance electron transport properties and adjust LUMO energy levels. These parameter changes improve device efficiency while maintaining structural simplicity suitable for OLED integration

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention designs composite molecular structures combining electron-withdrawing and electron-donating groups to achieve optimal electron transport and energy level alignment. This molecular composite approach improves efficiency without requiring complex device architectures

Inventive Principle:
Principle #40Composite materials

4Object-affected harmful factors

If conventional compounds are used, then environmental impact is not addressed, but performance improvement is needed

Engineering Contradiction:
Improveenvironmental impactVSAvoiddevice performance
Core Design Contradiction:
Object-affected harmful factorsVSProductivity

Solution Approach 1:

The patent modifies compound parameters to improve performance while selecting fluorinated and cyano-containing groups that have better environmental profiles. This approach addresses environmental concerns without sacrificing device performance through molecular design optimization

Inventive Principle:
Principle #35Parameter changes

Data Source

PatentEP4703366A1Compound of formula (i), organic electronic device comprising a compound of formula (i), display device comprising the organic electronic device as well as compounds of formula (i) for use in organic electronic devices
Publication Date: 2026.03.04 NOVALED GMBH
  • EP4703366A1 patent drawingFigure 1~2
  • EP4703366A1 patent drawingFigure 3~4
  • EP4703366A1 patent drawingFigure 5~6

AI summary

The present invention relates to a compound of formula (I) as well as to an organic electronic device comprising a semiconductor layer which comprises a compound of formula (I).