Organic Electroluminescence Device Using Condensed Nitrogen Heterocyclic Compound

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Solution Overview

Problem

Current organic electroluminescence devices face challenges in achieving high luminous efficiency while being driven at low voltage, with existing phosphorescent materials not adequately balancing high efficiency and durability.

Innovation Solution

Incorporating a highly condensed nitrogen-containing heterocyclic compound in the organic electroluminescence device's light emitting layer, which enhances electron injection and maintains hole injection properties, thereby improving charge balance and efficiency at lower voltages.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If phosphorescent materials (iridium complexes, platinum complexes) are used to improve luminous efficiency, then device efficiency increases, but device durability remains insufficient

Engineering Contradiction:
Improveluminous efficiencyVSAvoiddevice durability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent changes the chemical structure parameters of the organic compound by introducing a highly condensed nitrogen-containing heterocyclic ring system. This structural modification alters the electronic properties and charge transport characteristics, enabling the device to achieve high luminous efficiency through improved charge balance without relying solely on phosphorescent materials, thereby addressing the durability issue

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs a composite approach by combining the highly condensed nitrogen-containing heterocyclic compound with other organic materials in the light-emitting layer. This composite material strategy allows optimization of both efficiency and durability through synergistic effects of different materials with complementary properties

Inventive Principle:
Principle #40Composite materials

2Productivity

If conventional nitrogen-containing heterocyclic compounds are used to achieve high efficiency, then luminous efficiency improves, but operating voltage remains too high

Engineering Contradiction:
Improveluminous efficiencyVSAvoidoperating voltage
Core Design Contradiction:
ProductivityVSUse of energy by moving object

Solution Approach 1:

The patent modifies the molecular parameters of nitrogen-containing heterocyclic compounds by creating a highly condensed ring structure. This structural change optimizes the HOMO-LUMO energy levels and electron affinity, facilitating easier electron injection and reducing the operating voltage while maintaining high luminous efficiency

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces specific functional groups and structural features at localized positions within the heterocyclic compound. The highly condensed nitrogen-containing ring system creates localized regions with enhanced electron-accepting properties, which improve charge balance and reduce voltage requirements without compromising overall device efficiency

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of the condensed nitrogen-containing heterocyclic compound in the organic electroluminescence device leads to improved luminous efficiency and low-voltage operation by facilitating easier electron injection into the light emitting layer, resulting in a balanced charge transfer and enhanced device performance.

Implementation Method 1

enhances electron injection and maintains hole injection properties, thereby improving charge balance and efficiency at lower voltages

Methodology Applied
Scientific EffectElectron injection:

Implementation Method 2

An organic electroluminescence (EL) device is being watched as a promising display device because light emission with high brightness is obtained at a low voltage

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS8421066B2Organic electroluminescence device
Publication Date: 2013.04.16 UDC IRELAND
  • US8421066B2 patent drawing
  • US8421066B2 patent drawing
  • US8421066B2 patent drawing

AI summary

An organic electroluminescence device includes: a pair of electrodes; and at least one organic layer including a light emitting layer, the light emitting layer being provided between the pair of electrodes, wherein at least one layer of the at least one organic layer contains a compound represented by formula (1):wherein each of Z11 and Z12 independently represents an aromatic heterocyclic ring or an aromatic hydrocarbon ring; R11 represents a hydrogen atom or a substituent, provided that a plurality of R11s are the same or different; m represents an integer of 1 or more; and L1 represents a single bond or an m-valent linking group and is linked to any one of C atoms in R11, Z11 and Z12, provided that when m is 1, L1 does not exist.