OLED Double Emission Layers and Hole Blocking

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Solution Overview

Problem

Existing organic light-emitting devices (OLEDs) face challenges in achieving high efficiency and long lifespan due to issues with exciton formation and electron migration.

Innovation Solution

The implementation of a novel stack structure in OLEDs, featuring a first emission layer and a second emission layer with different hosts and light-emitting materials, along with a hole blocking layer, to enhance exciton formation and prevent hole migration.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Device complexity

If a single emission layer is used in OLEDs, then the device structure is simple, but the photoluminescence efficiency is insufficient and exciton formation is limited

Engineering Contradiction:
Improveemission layer structureVSAvoidphotoluminescence efficiency
Core Design Contradiction:
Device complexityVSLoss of energy

Solution Approach 1:

The emission layer is divided into multiple emission layers (first emission layer and second emission layer) with different hosts and light-emitting materials. Each emission layer generates excitons independently, increasing the total number of excitons formed and improving photoluminescence efficiency while maintaining reasonable structural complexity

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent introduces a vertical stacking dimension by arranging multiple emission layers at different positions between the electrodes. This multi-layer vertical structure allows exciton generation at multiple levels, enhancing overall light emission efficiency without significantly complicating the manufacturing process

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

2Use of energy by moving object

If electron transport region is present, then electron transport is enabled, but hole migration to the electron transport region causes energy loss and reduced device lifespan

Engineering Contradiction:
Improveelectron transport capabilityVSAvoidenergy loss from hole migration
Core Design Contradiction:
Use of energy by moving objectVSLoss of energy

Solution Approach 1:

A hole blocking layer is introduced as an intermediary component between the emission layer and the electron transport region. This layer selectively blocks hole migration toward the electron transport region while maintaining electron transport functionality, thereby preventing energy loss and improving device lifespan

Inventive Principle:
Principle #24Intermediary (Mediator)

3Productivity

If multiple emission layers with different hosts are used, then exciton formation is enhanced, but the device structure becomes more complex

Engineering Contradiction:
Improveexciton formation rateVSAvoidemission layer composition
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The emission region is segmented into multiple emission layers, each containing different host materials and light-emitting materials optimized for specific exciton generation purposes. This segmentation enables enhanced exciton formation through multiple independent emission pathways

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Each emission layer is designed with specific local quality characteristics - different host materials and light-emitting materials are selected for each layer to optimize exciton formation at that particular location. The first emission layer and second emission layer have distinct material compositions tailored to their specific functions

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration increases photoluminescence efficiency, reduces electron loss, and improves the lifespan of OLEDs by concentrating excitons at the interface between the emission layers and preventing hole migration to the electron transport region.

Implementation Method 1

The excitons may transit (e.g., transition or relax) from an excited state to a ground state, thus generating light

Methodology Applied
Scientific EffectPhotoluminescence: Photoluminescence

Data Source

PatentUS20250031572A1Organic light-emitting device
Publication Date: 2025.01.23 SAMSUNG DISPLAY CO LTD
  • US20250031572A1 patent drawing
  • US20250031572A1 patent drawing
  • US20250031572A1 patent drawing

AI summary

An organic light-emitting device includes: a first electrode; a second electrode facing the first electrode; an emission region between the first electrode and the second electrode and including a first emission layer and a second emission layer; and a hole blocking layer between the first emission layer and the first electrode, or between the second emission layer and the second electrode, wherein the second emission layer may be between the first emission layer and the hole blocking layer, the first emission layer may include a first host and a first light-emitting material, the second emission layer may include a second host and a second light-emitting material, and the first light-emitting material and the second light-emitting material may respectively be included in the first emission layer and the second emission layer at an identical ratio.