OLED Electron Transport Layer Using Dibenzofurane and Metal Complex

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Solution Overview

Problem

Existing organic light-emitting devices (OLEDs) face challenges in achieving high efficiency, long operational lifetimes, thermal stability, and low operating voltage.

Innovation Solution

An organic electronic device is designed with an organic layer comprising an organic metal complex of specific formula and a compound, which serves as the electron transport layer, optimizing the device structure to include an anode, hole injection layer, hole transport layer, light emitting layer, exciton blocking layer, electron transport layer, and cathode, with the organic layer constituting the electron transport layer to enhance efficiency and stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional electron transport materials are used in OLEDs, then device structure is simple, but efficiency and operational lifetime are insufficient

Engineering Contradiction:
Improvedevice efficiencyVSAvoidlayer structure complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent employs composite electron transport layers combining organic metal complexes (formula I) with dibenzofurane compounds (formulae II or III). This composite material approach achieves superior device efficiency and operational lifetime by leveraging the complementary properties of both materials, while maintaining a manageable layer structure through systematic material selection and combination.

Inventive Principle:
Principle #40Composite materials

2Loss of energy

If standard organic layers are used, then manufacturing is straightforward, but power efficiency and quantum efficiency are limited

Engineering Contradiction:
Improvepower efficiencyVSAvoidmanufacturing complexity
Core Design Contradiction:
Loss of energyVSEase of manufacture

Solution Approach 1:

The patent optimizes molecular parameters of the organic compounds used in the electron transport layer. By carefully selecting and adjusting structural parameters of the organic metal complex (formula I) and dibenzofurane compound (formulae II or III), the invention achieves enhanced power efficiency and quantum efficiency while maintaining feasibility of manufacturing through established organic electronics processes.

Inventive Principle:
Principle #35Parameter changes

3Use of energy by moving object

If conventional materials are used in electron transport layer, then operating voltage is high, but device stability is adequate

Engineering Contradiction:
Improveoperating voltageVSAvoidthermal stability
Core Design Contradiction:
Use of energy by moving objectVSReliability

Solution Approach 1:

The dibenzofurane compound (formulae II or III) acts as an intermediary material in the electron transport layer, working in conjunction with the organic metal complex (formula I). This intermediary approach enables reduced operating voltage while maintaining thermal stability, as the dibenzofurane compound mediates between the metal complex and the electrode, facilitating efficient electron transport with lower energy requirements and enhanced stability.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution results in OLEDs with superior lifetime, power efficiency, quantum efficiency, and reduced operating voltage, as demonstrated by comparative examples showing improved performance metrics.

Implementation Method 1

an organic layer interposed between the first electrode and the second electrode, wherein the organic layer comprises an organic metal complex of formula I and a compound of formula II, or III... which serves as the electron transport layer

Methodology Applied
Scientific EffectElectron transport: Conduction (electrical)

Implementation Method 2

The present invention provides an organic electronic device... superior lifetime, power efficiency, quantum efficiency, and reduced operating voltage... organic light-emitting devices

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS9203037B2Organic electronic devices comprising a layer of a dibenzofurane compound and a 8-hydroxypquinolinolato earth alkaline metal, or alkali metal complex
Publication Date: 2015.12.01 UDC IRELAND
  • US9203037B2 patent drawing
  • US9203037B2 patent drawing
  • US9203037B2 patent drawing

AI summary

The present invention provides an organic electronic device including a first electrode, a second electrode, and an organic layer interposed between the first electrode and the second electrode, wherein the organic layer comprises an organic metal complex of formulaand a compound of formulaThe organic electronic device, especially an organic light emitting device can show superior life time, power efficiency, quantum efficiency and/or a low operating voltage.