OLED Electron Transport Compound for Lifetime and Efficiency

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Solution Overview

Problem

Conventional organic light-emitting devices (OLEDs) using unimolecular materials for electron transport layers have short lifetimes, poor storage durability, and low reliability due to physical, chemical, and electrochemical changes, leading to issues like oxidation and delamination.

Innovation Solution

A novel compound represented by Formula 1, with specific electron injection and transport capabilities, is used in the OLED structure to enhance electrical characteristics, prevent crystallization, and improve emission efficiency, suitable for fluorescent or phosphorescent devices, reducing driving voltage and power consumption.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Duration of action of stationary object

If conventional unimolecular materials are used for electron transport layer, then device structure is simple, but lifetime is short and reliability is poor

Engineering Contradiction:
Improvedevice lifetimeVSAvoidoperational reliability
Core Design Contradiction:
Duration of action of stationary objectVSReliability

Solution Approach 1:

The patent employs composite materials by combining a host material with a guest material ( Formula 1 compound) to form an electron transport layer. This composite approach allows the host material to provide structural stability and the guest material to provide superior electron transport properties, thereby simultaneously improving device lifetime and reliability while avoiding the limitations of single unimolecular materials

Inventive Principle:
Principle #40Composite materials

2Stability of the object's composition

If conventional electron transport materials are used, then manufacturing process is simple, but storage durability is poor due to oxidation and delamination

Engineering Contradiction:
Improvestorage durabilityVSAvoidmanufacturing complexity
Core Design Contradiction:
Stability of the object's compositionVSEase of manufacture

Solution Approach 1:

The patent utilizes parameter changes by carefully optimizing the molecular structure parameters of the compound ( Formula 1), including substituent groups (R1-R6), ring structures (A), and linker groups (X). These parameter optimizations enhance the compound's chemical stability, resistance to oxidation, and adhesion properties, thereby improving storage durability while maintaining ease of manufacture through solution processing

Inventive Principle:
Principle #35Parameter changes

3Productivity

If existing host materials are used, then device structure is conventional, but emission efficiency is low and lifetime is short

Engineering Contradiction:
Improveemission efficiencyVSAvoidoperational lifetime
Core Design Contradiction:
ProductivityVSDuration of action of stationary object

Solution Approach 1:

The patent introduces a guest material ( Formula 1 compound) as an intermediary substance within the electron transport layer. This intermediary compound acts as a mediator that facilitates more efficient electron transport and enhances exciton management, thereby improving emission efficiency and extending operational lifetime without fundamentally altering the conventional OLED structure

Inventive Principle:
Principle #24Intermediary (Mediator)

4Power

If conventional materials are used, then driving voltage is high and power consumption is high, but material selection is straightforward

Engineering Contradiction:
Improvedriving voltageVSAvoidpower consumption
Core Design Contradiction:
PowerVSUse of energy by moving object

Solution Approach 1:

The patent applies parameter changes by optimizing the electronic structure parameters of the compound ( Formula 1), including HOMO/LUMO energy levels, electron mobility, and molecular packing characteristics. These parameter optimizations enable the material to facilitate electron transport at lower energy barriers, thereby reducing driving voltage and power consumption while maintaining straightforward manufacturing processes

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The novel compound results in OLEDs with improved lifetime, higher efficiency, and lower driving voltage, achieving high luminance and extended operational lifespan compared to existing host materials.

Implementation Method 1

a compound with electron injection and/or electron transport capabilities

Methodology Applied
Scientific EffectElectron injection:

Implementation Method 2

a compound with electron injection and/or electron transport capabilities

Methodology Applied
Scientific EffectElectron transport: Conduction (electrical)

Implementation Method 3

a high glass transition temperatures (Tg) enough to prevent crystallization

Methodology Applied
Scientific EffectGlass transition:

Implementation Method 4

The holes and electrons recombine in the EML to generate excitons. When the excitons drop from an excited state to a ground state, light is emitted

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS9559310B2Compound with electron injection and/or electron transport capabilities and organic light-emitting device including the same
Publication Date: 2017.01.31 SAMSUNG DISPLAY CO LTD
  • US9559310B2 patent drawing
  • US9559310B2 patent drawing
  • US9559310B2 patent drawing

AI summary

A compound represented by Formula 1 below and an organic light-emitting device including the compound are provided:Substituents in Formula 1 are the same as defined in the specification.