OLED Electron Transport Compound for Thermal Stability

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Solution Overview

Problem

Organic light-emitting devices face challenges with short luminescent lifespan and low durability due to material separation, chemical changes, and oxidation, especially in electron transport layers, leading to decreased color purity and reliability.

Innovation Solution

A compound represented by Formula 1 is used as an electron transport material, offering high glass transition temperature and melting point, enhancing heat resistance and durability, and improving the characteristics of organic light-emitting devices by incorporating it into the organic layer.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional electron transport materials are used in organic light-emitting devices, then the device can operate with basic electron transport function, but the device exhibits short luminescent lifespan and low durability due to material separation, chemical changes, and oxidation

Engineering Contradiction:
ImprovedurabilityVSAvoidluminescent lifespan
Core Design Contradiction:
ReliabilityVSDuration of action of stationary object

Solution Approach 1:

The patent employs a composite material strategy by combining a specific organic compound (Formula 1) with characteristic groups (L1, L2, R1-R18) that work synergistically. The core structure with electron-transporting characteristic groups is combined with specific substituent patterns that provide thermal stability and resistance to oxidation, creating a composite molecular structure that simultaneously achieves high durability and extended luminescent lifespan in OLED electron transport layers.

Inventive Principle:
Principle #40Composite materials

2Reliability

If electron transport materials are used in organic light-emitting devices, then electron transport function is achieved, but color purity decreases due to material separation and chemical changes

Engineering Contradiction:
Improvecolor purityVSAvoidmaterial stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent applies parameter changes by carefully adjusting the molecular structure parameters of the electron transport material. The compound in Formula 1 features specific characteristic groups (L1, L2, R1-R18) with controlled substituent patterns that optimize the balance between electron transport capability and compositional stability. By modifying parameters such as the types and positions of substituent groups, the material achieves both high color purity and enhanced stability against material separation and chemical changes.

Inventive Principle:
Principle #35Parameter changes

3Temperature

If standard organic materials are used in electron transport layers, then the device can be manufactured with conventional processes, but heat resistance is insufficient leading to decreased performance under thermal stress

Engineering Contradiction:
Improveheat resistanceVSAvoidmanufacturing complexity
Core Design Contradiction:
TemperatureVSEase of manufacture

Solution Approach 1:

The patent implements local quality by introducing specific heat-resistant characteristic groups (L1, L2, R1-R18) at strategic positions within the molecular structure of the electron transport material. Rather than uniformly modifying the entire material system, the invention places electron-transporting groups with inherent thermal stability at key locations in the molecule, providing localized heat resistance enhancement that maintains overall manufacturing simplicity while significantly improving thermal performance.

Inventive Principle:
Principle #3Local quality

Data Source

PatentUS10319919B2Compound and organic light-emitting device including the same
Publication Date: 2019.06.11 SAMSUNG DISPLAY CO LTD
  • US10319919B2 patent drawing
  • US10319919B2 patent drawing
  • US10319919B2 patent drawing

AI summary

An organic light-emitting device includes: a first electrode; a second electrode facing the first electrode; and an organic layer between the first electrode and the second electrode, the organic layer including an emission layer, wherein the organic layer comprises a compound represented by Formula 1. An organic light-emitting device including the compound may have high efficiency, low voltage, high luminance, and a long lifespan.