OLED Electron Transporting Region Using Rare Earth Telluride

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Solution Overview

Problem

Organic light emitting diode (OLED) display devices face challenges in maintaining electron injection efficiency and stability against oxidation, particularly when exposed to the atmosphere, which affects driving voltage and current efficiency.

Innovation Solution

Incorporating a tellurium compound of a rare earth metal, such as LaTe, CeTe, or YbTe, in the electron transporting region of the OLED, with a permittivity range of 5 to 12 and electronic polarizability of 8 to 15, along with a second electrode alloy of Ag, Mg, and Yb, to enhance electron injection and reduce oxidation effects.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional electron transporting materials are used in OLED, then device structure is simple, but electron injection efficiency deteriorates and oxidation resistance is poor

Engineering Contradiction:
Improveelectron injection efficiencyVSAvoidmaterial composition complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent uses composite materials by combining tellurium compounds of rare earth metals with conventional electron transporting materials. This composite approach improves electron injection efficiency and oxidation resistance while maintaining manageable device structure, directly resolving the contradiction between reliability and device complexity.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent changes the chemical and physical parameters of the electron transporting region by introducing tellurium compounds with specific properties (permittivity range of 5 to 12, electronic polarizability of 8 to 15). This parameter modification enhances electron injection efficiency without excessively complicating the device structure.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If conventional electron transporting materials are used in OLED, then manufacturing process is simple, but stability against oxidation deteriorates when exposed to atmosphere

Engineering Contradiction:
Improveoxidation resistanceVSAvoidmanufacturing process complexity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The composite material system combines tellurium compounds with conventional electron transporting materials, providing superior oxidation resistance. The manufacturing process remains relatively simple as the new material can be integrated into existing OLED fabrication processes, thus resolving the contradiction between reliability and ease of manufacture.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The tellurium compound acts as an intermediary material between the electrode and the emission layer, providing oxidation protection while facilitating electron transport. This intermediary approach improves oxidation resistance without significantly complicating the manufacturing process.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Reliability

If tellurium compound of rare earth metal is added to electron transporting region, then electron injection efficiency is improved, but material cost increases

Engineering Contradiction:
Improveelectron injection efficiencyVSAvoidmaterial cost
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The patent optimizes the concentration and properties of tellurium compounds to achieve the desired electron injection efficiency at minimal cost. By carefully controlling the permittivity (5-12) and electronic polarizability (8-15) parameters, the patent achieves high performance while managing material costs.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution improves the reliability and stability of the OLED by maintaining excellent electron injection efficiency and reducing physical property deterioration due to atmospheric exposure, resulting in improved light emitting efficiency and consistent performance.

Implementation Method 1

A permittivity of the tellurium compound of the rare earth metal may be in a range of 5 to 12

Methodology Applied
Scientific EffectPermittivity: Dielectric Permittivity

Implementation Method 2

An electronic polarizability of the tellurium compound of the rare earth metal may be in a range of 8 to 15

Methodology Applied
Scientific EffectElectronic polarizability: Polarisation

Implementation Method 3

electrons injected from one electrode and holes injected from another electrode are combined with each other in a light emitting layer thereby generating excitons, and energy is outputted from the excitons to emit light

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS10418576B2Light emitting diode and display device including the same
Publication Date: 2019.09.17 SAMSUNG DISPLAY CO LTD
  • US10418576B2 patent drawing
  • US10418576B2 patent drawing
  • US10418576B2 patent drawing

AI summary

A light emitting diode including a first electrode; a second electrode overlapping the first electrode; an emission layer positioned between the first electrode and the second electrode; and an electron transporting region positioned between the second electrode and the emission layer, wherein the electron transporting region includes a tellurium compound of a rare earth metal.