OLED Emission Layer Composition for Energy Level Alignment

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Solution Overview

Problem

Existing organic light-emitting devices face challenges in achieving optimal energy level alignment and efficiency in their components, which affects their performance and functionality.

Innovation Solution

The development of novel compositions comprising specific compounds with defined HOMO and LUMO energy levels, represented by Formula 1, to enhance the alignment and efficiency of charge transport and recombination in organic light-emitting devices.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If conventional organic light-emitting devices use standard organic compounds, then the device structure is simple and manufacturing is easier, but the energy level alignment is suboptimal and device efficiency is reduced

Engineering Contradiction:
Improveease of manufactureVSAvoiddevice efficiency
Core Design Contradiction:
Ease of manufactureVSProductivity

Solution Approach 1:

The patent applies parameter changes by carefully selecting organic compounds with specific HOMO and LUMO energy levels. The first compound has HOMO of -5.5 eV or higher and LUMO of -2.8 eV or less, while the second compound has HOMO of -5.5 eV or higher. These parameter specifications optimize energy level alignment between layers, improving charge transport and recombination efficiency without complicating the manufacturing process

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite materials by combining multiple organic compounds with complementary properties. The emission layer comprises both a first compound (with specific HOMO/LUMO levels) and a second compound (with specific HOMO level), creating a composite organic layer that achieves superior energy level alignment and charge transport characteristics compared to single-compound systems

Inventive Principle:
Principle #40Composite materials

2Productivity

If the organic layer uses compounds with optimized HOMO and LUMO energy levels, then charge transport and recombination efficiency improve, but the selection and synthesis become more complex

Engineering Contradiction:
Improvecharge transport efficiencyVSAvoiddevice complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent systematically controls energy level parameters by specifying HOMO of -5.5 eV or higher and LUMO of -2.8 eV or less for the first compound. This parameter optimization enhances charge transport efficiency through improved energy level alignment with adjacent layers, while the clear specification criteria actually simplifies the material selection process

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies local quality by assigning specific energy level characteristics to specific layers. The first compound in the emission layer has optimized HOMO/LUMO levels for efficient charge injection and transport, while the second compound has optimized HOMO level for complementary charge transport. Each compound performs its specific function with locally optimized properties

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The proposed compounds improve the performance of organic light-emitting devices by optimizing energy levels, leading to enhanced light emission and device efficiency.

Implementation Method 1

the second compound has a highest occupied molecular orbital (HOMO) energy level of about −5.5 eV or higher, and the third compound has a lowest unoccupied molecular orbital (LUMO) energy level of about −2.8 eV or less

Methodology Applied
Scientific EffectEnergy level alignment:

Implementation Method 2

The holes and the electrons recombine in the emission layer to produce excitons. These excitons transition from an excited state to a ground state to thereby generate light

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS12540151B2Composition and organic light-emitting device including the same
Publication Date: 2026.02.03 SAMSUNG DISPLAY CO LTD
  • US12540151B2 patent drawing
  • US12540151B2 patent drawing
  • US12540151B2 patent drawing

AI summary

Provided are a compound and an organic light-emitting device including the same. The composition includes a first compound represented by Formula 1, a second compound having a highest occupied molecular orbital (HOMO) energy level of −5.5 eV, and a third compound having a lowest unoccupied molecular orbital (LUMO) energy level of −2.8 eV or less.M(L1)n1(L2)n2  Formula 1M, L1, L2, n1, and n2 in Formula 1 are the same as described in the present specification.