OLED Emission Layer Charge Balance via Composite Materials

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Solution Overview

Problem

Current organic light-emitting devices face challenges in achieving balanced charge transport and efficient light emission, leading to limitations in efficiency and lifespan.

Innovation Solution

An organic light-emitting device is designed with an emission layer comprising specific compounds represented by Formulas 1, 2, and 3, which include a first compound for charge balance, a second compound with suitable reverse intersystem crossing efficiency, and a third compound for red fluorescence, optimized in weight percentages to enhance efficiency and lifespan.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional organic light-emitting devices use standard emission layers, then device structure is simple, but charge transport balance is poor and efficiency is limited

Engineering Contradiction:
Improvelight emission efficiencyVSAvoidemission layer composition complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The emission layer uses a composite material system comprising three specific compounds: a first compound (Formula 1) with charge balance functionality, a second compound (Formula 2) with reverse intersystem crossing efficiency, and a third compound (Formula 3) for red fluorescence emission. This composite approach enables simultaneous optimization of charge transport balance, exciton management, and light emission efficiency, resolving the contradiction between improved productivity and increased device complexity.

Inventive Principle:
Principle #40Composite materials

2Duration of action of moving object

If conventional organic light-emitting devices use standard materials, then manufacturing is simple, but lifespan is limited

Engineering Contradiction:
Improvedevice lifespanVSAvoidmanufacturing process complexity
Core Design Contradiction:
Duration of action of moving objectVSEase of manufacture

Solution Approach 1:

The patent specifies precise weight percentage ranges for each compound in the emission layer: first compound (60-90 wt%), second compound (10-40 wt%), and third compound (0.5-5 wt%). These parameter optimizations ensure balanced charge transport, efficient exciton utilization through reverse intersystem crossing, and stable red fluorescence emission. The controlled parameter ranges improve device lifespan while maintaining manufacturing feasibility through defined material specifications.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The device achieves improved charge balance, efficiency, and lifespan by utilizing the specified compounds, ensuring high color purity and efficient light emission within the 520 nm to 780 nm range.

Implementation Method 1

a second compound with suitable reverse intersystem crossing efficiency

Methodology Applied
Scientific EffectReverse intersystem crossing:

Implementation Method 2

a third compound for red fluorescence, ensuring high color purity and efficient light emission within the 520 nm to 780 nm range

Methodology Applied
Scientific EffectFluorescence emission: Fluorescence

Implementation Method 3

Carriers, such as holes and electrons, recombine in the emission layer to produce excitons. These excitons transit from an excited state to a ground state, thereby generating light.

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS11690287B2Organic light-emitting device and display apparatus including the same
Publication Date: 2023.06.27 SAMSUNG DISPLAY CO LTD
  • US11690287B2 patent drawing
  • US11690287B2 patent drawing
  • US11690287B2 patent drawing

AI summary

An organic light-emitting device includes a first electrode; a second electrode; and an organic layer between the first electrode and the second electrode. The organic layer includes an emission layer. The emission layer includes a first compound, a second compound, and a third compound. The first compound is represented by Formula 1, the second compound is represented by Formula 2, the third compound is represented by Formula 3, and the first compound and the second compound are different from each other.