OLED Emission Layer Organometallic Compound Charge Balance

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Solution Overview

Problem

Organic light-emitting devices (OLEDs) face challenges in achieving balanced hole and electron injection, leading to suboptimal color coordinates, efficiency, and lifetime.

Innovation Solution

Incorporating a specific organometallic compound in the emission layer, represented by Formula 1, which includes iridium or other metals, along with auxiliary and host materials in the hole transport region, to enhance the balance of charge carriers and improve light emission characteristics.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional dopant materials are used in the emission layer, then the device structure is simple, but the color coordinates are poor and the balance between holes and electrons is insufficient

Engineering Contradiction:
Improvebalance between holes and electronsVSAvoidemission layer composition
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The emission layer uses a composite material system comprising a host material (Compound 1 or Compound 2), a dopant material (Formula 1 compound), and an auxiliary material (Formula 2 compound). This composite approach enables balanced charge carrier injection and improved color coordinates while maintaining device performance

Inventive Principle:
Principle #40Composite materials

2Illumination intensity

If the emission layer uses only host and dopant materials, then the material composition is simple, but the color coordinates and efficiency are suboptimal

Engineering Contradiction:
Improvecolor coordinatesVSAvoidemission layer materials
Core Design Contradiction:
Illumination intensityVSDevice complexity

Solution Approach 1:

The auxiliary material (Formula 2 compound) is specifically introduced to modify local properties of the emission layer, improving color coordinates and charge balance. Each component (host, dopant, auxiliary) performs a specific function: host provides the matrix, dopant provides luminescence, and auxiliary material optimizes charge carrier balance and color properties

Inventive Principle:
Principle #3Local quality

3Productivity

If balanced charge carrier injection is achieved through material optimization, then efficiency and lifetime improve, but the manufacturing process becomes more complex

Engineering Contradiction:
Improvedevice efficiencyVSAvoidemission layer fabrication
Core Design Contradiction:
ProductivityVSEase of manufacture

Solution Approach 1:

The patent optimizes specific parameters including the concentration ratio of dopant to auxiliary material (0.1-10:1 by weight), the molecular structure parameters of the organometallic compound (Formula 1), and the host-guest interaction parameters. These parameter optimizations achieve balanced charge injection and improved efficiency while maintaining manufacturability through well-defined composition ranges

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution results in OLEDs with improved color coordinates, efficiency, and extended lifetime by optimizing the balance of holes and electrons, leading to enhanced light emission characteristics without significant increases in driving voltage.

Implementation Method 1

Holes injected from the anode move to the emission layer via the hole transport region, while electrons injected from the cathode move to the emission layer via the electron transport region. Carriers such as the holes and electrons recombine together in the emission layer to generate exitons. When these exitons drop from an excited state to a ground state, light is emitted.

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentEP3010068B1Organic light-emitting device
Publication Date: 2020.12.09 SAMSUNG DISPLAY CO LTD
  • EP3010068B1 patent drawingFigure 1
  • EP3010068B1 patent drawing
  • EP3010068B1 patent drawing

AI summary

An organic light-emitting device includes: a first electrode; a second electrode disposed opposite to the first electrode; an emission layer between the first electrode and the second electrode; and a hole transport region between the first electrode and the emission layer, wherein the emission layer includes an organometallic compound of Formula 1 as represented in the specification, and the hole transport region includes a first compound of Formula 2A or Formula 2B as represented in the specification.