Organic Light-Emitting Device Emission Layer Host Material Balance

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Solution Overview

Problem

Conventional organic light-emitting devices face challenges in balancing hole and electron mobility, leading to poor durability and reduced lifespan due to the difficulty in concurrently achieving electron transport and hole transport capabilities within a single host material in the emission layer.

Innovation Solution

Incorporating a first material and a second material, represented by specific organic layer formulas, into the emission layer to balance hole and electron mobility, with the second material providing high thermal stability and durability, and optionally including a phosphorescent dopant for enhanced light-emission characteristics.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a single host material is used in the emission layer, then the device structure is simple, but hole and electron mobility cannot be balanced, leading to poor durability and reduced lifespan

Engineering Contradiction:
Improvedevice lifespanVSAvoidemission layer composition
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The emission layer uses a composite host system comprising a first host material and a second host material with different functional characteristics. The first host material provides hole transport capability while the second host material provides electron transport capability, achieving balanced carrier mobility and improved device reliability without excessive complexity

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The host material system is segmented into distinct functional components: a first host material optimized for hole transport and a second host material optimized for electron transport. This segmentation allows each material to specialize in one carrier type, resolving the contradiction between simplicity and balanced mobility

Inventive Principle:
Principle #1Segmentation

2Reliability

If conventional host materials are used, then the material selection is easy, but thermal stability and durability under electric stress are insufficient

Engineering Contradiction:
Improvethermal stabilityVSAvoidmaterial selection
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent specifies particular molecular weight ranges and structural parameters for the host materials to ensure optimal thermal stability and electrical performance. By controlling these parameters within defined ranges, the invention achieves high reliability while maintaining reasonable ease of manufacture through established material classes

Inventive Principle:
Principle #35Parameter changes

3Speed

If the emission layer is optimized for one carrier type, then carrier mobility for that type is high, but the other carrier mobility remains unbalanced, reducing overall device performance

Engineering Contradiction:
Improvecarrier mobilityVSAvoidmobility balance
Core Design Contradiction:
SpeedVSReliability

Solution Approach 1:

The host material system exhibits local quality differentiation where the first host material is optimized specifically for hole transport and the second host material is optimized specifically for electron transport. This localized optimization of different regions (material components) achieves overall mobility balance while maintaining high speed for both carrier types

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The balanced mobility and durability of the organic light-emitting device result in improved efficiency and extended lifespan, with the emission layer achieving high thermal stability and robustness against electric stress.

Implementation Method 1

Holes provided from the first electrode may move toward the emission layer through the hole transport region, and electrons provided from the second electrode may move toward the emission layer through the electron transport region

Methodology Applied
Scientific EffectCharge transport: Conduction (electrical)

Implementation Method 2

Carriers (e.g., holes and electrons) are then recombined in the emission layer to produce excitons. When these excitons change from an excited state to a ground state, light is emitted

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Implementation Method 3

optionally including a phosphorescent dopant for enhanced light-emission characteristics

Methodology Applied
Scientific EffectPhosphorescence: Phosphorescence

Data Source

PatentUS10305041B2Organic light-emitting device
Publication Date: 2019.05.28 SAMSUNG DISPLAY CO LTD
  • US10305041B2 patent drawing
  • US10305041B2 patent drawing
  • US10305041B2 patent drawing

AI summary

An organic light-emitting device including a first electrode; a second electrode; and an organic layer between the first electrode and the second electrode and including an emission layer. The organic layer includes a first material represented by Formula 1 and a second material represented by Formula 2:The resulting organic light-emitting device may have high efficiency and a long lifespan.