Organometallic OLED Emitters for Saturated Color

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Solution Overview

Problem

Current organic light-emitting diode (OLED) technologies face challenges in achieving saturated colors, particularly in red, green, and blue emissions, which are essential for full-color displays, and there is a need for materials that can efficiently emit light while being cost-effective and flexible.

Innovation Solution

A compound of Formula I is introduced, where Z1-Z8 are independently C or N, with specific substitution patterns and RA representing various groups, forming a compound that can be used in OLEDs as an emitter or host, enhancing the organic layer's performance and enabling the production of saturated colors.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If conventional materials are used in OLEDs, then cost is reduced, but emission efficiency and color saturation are insufficient

Engineering Contradiction:
ImprovecostVSAvoidemission efficiency
Core Design Contradiction:
Ease of manufactureVSProductivity

Solution Approach 1:

The patent modifies the molecular structure of organic emissive materials by changing chemical parameters (adding specific substituents like carbazole, triphenylene, and dibenzofuran groups) to improve emission efficiency and color saturation while maintaining cost-effectiveness through synthetic organic chemistry

Inventive Principle:
Principle #35Parameter changes

2Device complexity

If conventional materials are used in OLEDs, then manufacturing simplicity is maintained, but color saturation is insufficient

Engineering Contradiction:
Improvemanufacturing simplicityVSAvoidcolor saturation
Core Design Contradiction:
Device complexityVSIllumination intensity

Solution Approach 1:

The patent introduces specific functional groups and substituents at particular positions in the molecular structure (local modifications) to achieve saturated red, green, and blue emissions, allowing different regions of the molecular structure to contribute differently to color properties while maintaining overall manufacturing simplicity

Inventive Principle:
Principle #3Local quality

3Adaptability or versatility

If organic materials are used, then flexibility and cost advantages are achieved, but performance (emission efficiency) is insufficient

Engineering Contradiction:
ImproveflexibilityVSAvoidemission efficiency
Core Design Contradiction:
Adaptability or versatilityVSProductivity

Solution Approach 1:

The patent creates composite organic emissive materials by combining multiple functional moieties (electron-donating and electron-withdrawing groups, aromatic rings, heterocyclic structures) within single molecular frameworks to achieve both the flexibility inherent in organic materials and enhanced emission efficiency through synergistic interactions of different structural components

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The compound improves the emission efficiency and color saturation in OLEDs, allowing for the creation of high-performance, cost-effective, and flexible full-color displays by optimizing the organic layer's properties.

Implementation Method 1

OLEDs make use of thin organic films that emit light when voltage is applied across the device

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS20230389421A1Organic electroluminescent materials and devices
Publication Date: 2023.11.30 UNIVERSAL DISPLAY CORP
  • US20230389421A1 patent drawing
  • US20230389421A1 patent drawing
  • US20230389421A1 patent drawing

AI summary

Provided are organometallic compounds comprising a polycyclic structure with at least two heteroaromatic rings, wherein at least two nitrogen-containing groups are bonded to a first of the at least two heteroaromatic rings and at least group RA selected from NR5R6 or SiR7R8R9 is bonded to a second of the at least two heteroaromatic rings. Also provided are formulations comprising these organometallic compounds. Further provided are organic light emitting devices (OLEDs) and related consumer products that utilize these organometallic compounds.