Organic Light-Emitting Device Energy Transfer Optimization

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Solution Overview

Problem

Existing organic light-emitting devices face challenges in achieving low driving voltage, high efficiency, and long lifespan due to inefficiencies in energy transfer and balance between hole and electron transport.

Innovation Solution

Incorporating a first compound and a second compound in the organic layer, specifically designed to facilitate effective energy transfer and balance between hole and electron transport, with the first compound in the emission auxiliary layer and the second compound in the emission layer, allowing for efficient energy transfer from host to dopant and balanced charge transport.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If conventional organic light-emitting devices are used, then basic light emission is achieved, but high driving voltage and low efficiency result due to poor energy transfer and unbalanced charge transport

Engineering Contradiction:
Improveenergy transfer efficiencyVSAvoiddriving voltage
Core Design Contradiction:
Loss of energyVSPower

Solution Approach 1:

The patent introduces a hole transport layer as an intermediary between the emission layer and the anode. This layer mediates charge transport by facilitating hole injection from the anode to the emission layer, improving energy transfer efficiency and reducing the driving voltage required for device operation

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent modifies the energy level parameters of the organic compounds used in different layers. By selecting materials with appropriate HOMO and LUMO levels, the energy barriers for charge injection and transport are optimized, enabling efficient energy transfer and balanced charge transport that reduces driving voltage

Inventive Principle:
Principle #35Parameter changes

2Reliability

If conventional organic light-emitting devices are used, then basic light emission is achieved, but short lifespan results due to unbalanced hole and electron transport

Engineering Contradiction:
Improvedevice lifespanVSAvoidcharge transport balance
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent assigns different functional properties to different layers of the device. The hole transport layer is specifically designed with high hole mobility and appropriate energy levels to facilitate hole transport, while the emission layer is optimized for radiative recombination. This local optimization of material properties ensures balanced charge transport throughout the device, improving reliability and lifespan

Inventive Principle:
Principle #3Local quality

3Productivity

If simple organic layers are used, then device structure is simple, but low efficiency results due to insufficient energy transfer from host to dopant

Engineering Contradiction:
Improvelight emission efficiencyVSAvoidorganic layer structure
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent divides the organic layer into functionally distinct segments: an emission layer containing dopant molecules dispersed in a host matrix, and a separate hole transport layer. This segmentation allows each layer to be optimized for its specific function - the emission layer for efficient energy transfer and light emission, and the hole transport layer for balanced charge transport - thereby improving overall device efficiency

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration results in an organic light-emitting device with low driving voltage, high efficiency, and extended lifespan by optimizing energy transfer and charge balance.

Implementation Method 1

efficient energy transfer from host to dopant

Methodology Applied
Scientific EffectEnergy transfer: Fluorescence

Implementation Method 2

Carriers, such as holes and electrons, recombine in the emission layer to produce excitons. These excitons transition from an excited state to a ground state, thereby generating light.

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Implementation Method 3

Holes provided from the first electrode may move toward the emission layer through the hole transport region, and electrons provided from the second electrode may move toward the emission layer through the electron transport region

Methodology Applied
Scientific EffectCharge transport: Conduction (electrical)

Implementation Method 4

Carriers, such as holes and electrons, recombine in the emission layer to produce excitons

Methodology Applied
Scientific EffectCarrier recombination: Electroluminescence

Data Source

PatentUS10665789B2Organic light-emitting device
Publication Date: 2020.05.26 SAMSUNG DISPLAY CO LTD
  • US10665789B2 patent drawing
  • US10665789B2 patent drawing
  • US10665789B2 patent drawing

AI summary

An organic light-emitting device having a low driving voltage, high efficiency, and a long lifespan is provided. The device includes a first electrode, a second electrode, and an organic layer between the first electrode and the second electrode, wherein the organic layer includes an emission layer, a first compound, and a second compound. Various chemical structures for the first compound and the second compound are provided.