Heterocyclic OLED Organic Layers for Faster Charge Recombination

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Solution Overview

Problem

Existing organic light-emitting devices (OLEDs) face challenges in enhancing their performance in terms of luminance, driving voltage, and response speed, while maintaining wide viewing angles and high contrast ratios.

Innovation Solution

Incorporation of heterocyclic compounds represented by specific formulas into the organic layer of OLEDs, which include substituted or unsubstituted C5-C30 carbocyclic and C1-C30 heterocyclic groups, to improve charge transport and recombination efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If heterocyclic compounds are incorporated into the organic layer to improve charge transport, then luminance and response speed are enhanced, but driving voltage increases

Engineering Contradiction:
ImproveluminanceVSAvoiddriving voltage
Core Design Contradiction:
ProductivityVSUse of energy by stationary object

Solution Approach 1:

The patent modifies the chemical structure of heterocyclic compounds by introducing specific substituents (electron-donating or electron-withdrawing groups) to adjust HOMO and LUMO energy levels. This parameter optimization enables improved charge transport efficiency without excessive voltage increase, resolving the contradiction between luminance enhancement and energy consumption.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite organic layer structures combining heterocyclic compounds with other functional materials (host materials, dopants) to achieve synergistic effects. The heterocyclic compound serves as a charge transport mediator within the composite, improving luminance while the overall composition is optimized to maintain acceptable driving voltage levels.

Inventive Principle:
Principle #40Composite materials

2Speed

If heterocyclic compounds are incorporated into the organic layer to improve charge transport, then response speed is enhanced, but device complexity increases

Engineering Contradiction:
Improveresponse speedVSAvoiddevice complexity
Core Design Contradiction:
SpeedVSDevice complexity

Solution Approach 1:

The patent optimizes molecular parameters of heterocyclic compounds (molecular weight, conjugation length, substituent types) to achieve fast charge transport. By carefully selecting parameters within specific ranges, the patent attains high response speed while avoiding excessive structural complexity that would complicate device fabrication and processing.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enhances luminance, reduces driving voltage, and increases response speed, thereby improving overall OLED performance without compromising viewing angle and contrast ratio.

Implementation Method 1

Incorporation of heterocyclic compounds represented by specific formulas into the organic layer of OLEDs, which include substituted or unsubstituted C5-C30 carbocyclic and C1-C30 heterocyclic groups, to improve charge transport and recombination efficiency

Methodology Applied
Scientific EffectCharge transport: Conduction (electrical)

Implementation Method 2

The holes and the electrons recombine in the emission layer to produce excitons. These excitons transition from an excited state to a ground state, thereby generating light

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentEP4141012B1Heterocyclic compound, organic light-emitting device including the heterocyclic compound, and electronic apparatus including the organic light-emitting device
Publication Date: 2025.11.19 SAMSUNG DISPLAY CO LTD
  • EP4141012B1 patent drawingFigure 1
  • EP4141012B1 patent drawingFigure 2
  • EP4141012B1 patent drawingFigure 3

AI summary

Provided are a heterocyclic compound represented by Formula 1-1 or 1-2, an organic light-emitting device including the heterocyclic compound, and an electronic apparatus including the organic light-emitting device: wherein Formulae 1-1 and 1-2 are respectively the same as described in the present specification.