Heterocyclic OLED Materials for Lower Voltage and Longer Lifetime

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Solution Overview

Problem

Current organic light emitting devices face challenges in efficiency and stability due to the limitations of existing materials used in their organic material layers.

Innovation Solution

A heterocyclic compound, as described by Chemical Formula 1, is introduced for use in the organic material layers of organic light emitting devices, enhancing efficiency and reducing driving voltage while improving the device's lifetime.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional organic materials are used in the organic material layer, then the device structure can be maintained, but the efficiency and lifetime of the organic light emitting device are insufficient

Engineering Contradiction:
Improvedevice efficiencyVSAvoiddevice lifetime
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent modifies the chemical structure of organic compounds by introducing specific heterocyclic groups (triazine, pyrimidine, pyridine rings) and substituent patterns to optimize electronic properties including HOMO/LUMO energy levels, charge mobility, and molecular packing. These parameter changes in molecular structure directly improve both device efficiency and lifetime simultaneously

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite organic material systems combining the newly developed heterocyclic compounds with other organic materials in the organic material layer. This composite approach leverages the complementary properties of different materials to achieve enhanced efficiency and improved device stability and lifetime

Inventive Principle:
Principle #40Composite materials

2Power

If existing organic materials are used, then the device can operate, but the driving voltage remains high

Engineering Contradiction:
Improvedriving voltageVSAvoiddevice efficiency
Core Design Contradiction:
PowerVSProductivity

Solution Approach 1:

The patent optimizes the energy level parameters (HOMO and LUMO) of the organic compounds through systematic molecular design. By adjusting these energy level parameters to match the electrode work functions and adjacent layer energy levels, the device achieves lower driving voltage without sacrificing efficiency

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces specific functional groups and substituent patterns at particular positions within the molecular structure to locally optimize charge injection and transport properties. This local structural optimization enables reduced driving voltage while maintaining overall device efficiency

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The heterocyclic compound improves the efficiency and extends the lifetime of organic light emitting devices by optimizing the performance of the organic material layers, specifically the light emitting layer, when used in various layer configurations within the device.

Implementation Method 1

An organic light emission phenomenon generally refers to a phenomenon converting electrical energy to light energy using an organic material

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS11767315B2Heterocyclic compound and organic light-emitting device including same
Publication Date: 2023.09.26 LG CHEM LTD
  • US11767315B2 patent drawing
  • US11767315B2 patent drawing
  • US11767315B2 patent drawing

AI summary

Provided is a heterocyclic compound of Chemical Formula 1:wherein:X1 to X3 are each independently is N or CH;at least two of X1 to X3 are N;Y is O or S;R1 to R6 each independently is hydrogen, deuterium, a halogen group, a nitrile group, or a substituted or unsubstituted: alkyl, silyl, aryl or heteroaryl group;Ar1 and Ar2 each independently is a substituted or unsubstituted aryl or heteroaryl group;L1 and L2 each independently is a direct bond, or a substituted or unsubstituted arylene or heteroarylene group;Z is a nitrile group, a halogen group, or a substituted or unsubstituted: alkyl, silyl, aryl or heteroaryl group;n is an integer of 0 to 2; anda and b are an integer of 0 to 5,and an organic light-emitting device including the same.