OLED Hole Transport Layer Structure for Balanced Charge Recombination

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Existing organic light emitting devices face challenges in optimizing the hole transport layers to enhance efficiency and performance, particularly in the recombination of holes and electrons for improved light emission.

Innovation Solution

Incorporating specific hole transport materials represented by Formulas 1 to 4, along with a thermally activated delayed fluorescence emission material in the emission layer, to optimize the hole transport region and enhance the recombination of holes and electrons.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional hole transport materials are used, then device structure is simple, but emission efficiency is low and device life is short

Engineering Contradiction:
Improveemission efficiencyVSAvoidhole transport region structure
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The hole transport region is divided into multiple layers (hole injection layer, first hole transport layer, second hole transport layer) with different materials and functions. Each layer is optimized for specific charge transport requirements, resulting in improved emission efficiency and device life through balanced charge transport.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent employs composite material structures in the hole transport region, combining materials with different properties (e.g., high hole mobility materials, materials with specific LUMO levels) to achieve optimal charge transport and balance between holes and electrons, thereby improving emission efficiency.

Inventive Principle:
Principle #40Composite materials

2Reliability

If inadequate material selection is used in hole transport region, then manufacturing is easier, but charge transport balance is poor

Engineering Contradiction:
Improvecharge transport balanceVSAvoidmaterial selection and deposition
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent optimizes key parameters of hole transport materials including HOMO levels (5.5-6.5 eV), LUMO levels (2.0-3.5 eV), and hole mobility (10^-6 to 10^-3 cm²/Vs). These parameter specifications ensure proper charge transport balance while maintaining compatibility with standard manufacturing processes.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The hole transport layers act as intermediaries between the anode and the emission layer, facilitating balanced charge transport. The materials are selected to mediate between the high work function anode and the emission layer, ensuring proper hole injection and transport without requiring complex manufacturing processes.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The proposed configuration improves the efficiency and performance of organic light emitting devices by optimizing the hole transport layers, leading to enhanced light emission and device performance.

Implementation Method 1

holes and electrons injected from an anode and a cathode recombine in an emission layer, and a luminescent material including an organic compound in the emission layer emits light

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Implementation Method 2

The emission layer may include an emission material containing a donor and an acceptor, the emission material being a thermally activated delayed fluorescence material

Methodology Applied
Scientific EffectThermally activated delayed fluorescence: Phosphorescence

Data Source

PatentUS12410120B2Organic light emitting device
Publication Date: 2025.09.09 SAMSUNG DISPLAY CO LTD
  • US12410120B2 patent drawing
  • US12410120B2 patent drawing
  • US12410120B2 patent drawing

AI summary

An organic light emitting device including an anode; a hole transport region on the anode; an emission layer on the hole transport region; an electron transport region on the emission layer; and a cathode on the electron transport region, wherein the hole transport region includes: a first hole transport layer including a first hole transport material represented by the following Formula 1 or a second hole transport material represented by the following Formula 2; and a second hole transport layer on the first hole transport layer, the second hole transport layer including a third hole transport material represented by the following Formula 3 or a fourth hole transport material represented by the following Formula 4: