OLED Hole-Transporting Compound with Extended Phenylene Linkers

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Solution Overview

Problem

Current hole-transporting compounds used in OLEDs, particularly those with carbazole and triarylamino groups, face limitations in efficiency and lifespan, especially in hole transport and electron blocking layers.

Innovation Solution

A compound with a carbazole unit and an arylamino unit connected via three or more phenylene units is developed, enhancing performance and device longevity by optimizing hole-transporting properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional hole-transporting compounds with carbazole and triarylamino groups are used, then basic hole transport function is achieved, but efficiency and lifespan of OLEDs are limited

Engineering Contradiction:
Improvedevice lifespanVSAvoiddevice efficiency
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent changes the structural parameters of hole-transporting compounds by extending the phenylene linker units to three or more phenylene units between carbazole and triarylamino groups, optimizing the distance and arrangement of functional groups to improve both efficiency and lifespan

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates composite molecular structures combining carbazole units, extended phenylene linker units (three or more), and triarylamino units in specific configurations to achieve synergistic effects that improve both device efficiency and reliability

Inventive Principle:
Principle #40Composite materials

2Reliability

If compounds with three or more phenylene units between carbazole and triarylamino groups are used, then device efficiency and lifespan are significantly improved, but molecular complexity increases

Engineering Contradiction:
Improvedevice lifespanVSAvoidmolecular structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent segments the molecule into distinct functional units (carbazole group, extended phenylene linker units, triarylamino group) that can be independently optimized and combined in various configurations while maintaining overall functionality

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The extended phenylene linker units serve multiple functions: they provide structural separation, enable optimal spacing between functional groups, facilitate charge transport, and allow for various substitution patterns, making the molecular scaffold universally applicable for different device requirements

Inventive Principle:
Principle #6Universality (Multi-functionality)

Data Source

PatentEP2922932B1Materials for electronic devices
Publication Date: 2019.06.12 MERCK PATENT GMBH
  • EP2922932B1 patent drawing
  • EP2922932B1 patent drawing
  • EP2922932B1 patent drawing

AI summary

The present application relates to a compound according to formula (I), and the use thereof as a functional material in an electronic device. The compound according to formula (I) is preferably used as a hole-transporting material in an organic electroluminescence device (OLED).