OLED Emission Layer Host-Dopant Balance for Efficiency and Lifespan

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Current organic light-emitting devices (OLEDs) face challenges in achieving high efficiency and long lifespan due to imbalances in electron and hole transport, which affect their performance and durability.

Innovation Solution

Incorporating specific organic compounds represented by Formulae 1-1 to 1-3 and Formula 2 into the emission layer, which include a combination of fluorescent and phosphorescent characteristics, along with electron transporting and bipolar properties, to enhance electron and hole balance, thermal stability, and light emission efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional organic compounds are used in the emission layer, then the device structure is simple, but the electron-hole transport balance is poor leading to low efficiency and short lifespan

Engineering Contradiction:
Improvelight emission efficiencyVSAvoiddevice lifespan
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent employs a composite material system consisting of a host compound (Formula 1-1 to 1-3) and a dopant compound (Formula 2) in the emission layer. The host compound provides bipolar charge transport properties and thermal stability, while the dopant compound contributes fluorescent and phosphorescent characteristics. This composite approach enables simultaneous improvement of light emission efficiency through enhanced electron-hole balance and device lifespan through superior thermal stability and charge transport balance.

Inventive Principle:
Principle #40Composite materials

2Productivity

If compounds with enhanced electron transporting properties are used, then electron-hole balance improves, but driving voltage increases

Engineering Contradiction:
Improveelectron-hole transport balanceVSAvoiddriving voltage
Core Design Contradiction:
ProductivityVSUse of energy by moving object

Solution Approach 1:

The patent applies local quality by designing the host compound (Formula 1-1 to 1-3) with specific functional groups positioned at particular locations in the molecular structure. The compounds contain electron-donating groups (such as carbazole, triphen胺) and electron-withdrawing groups (such as fluorinated aromatic rings) arranged to create optimal charge distribution. This localized functional group arrangement enables improved electron-hole transport balance without causing significant increases in driving voltage, as the charge transport enhancement is achieved through molecular design rather than increased energy input.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The combination of these compounds improves the balance of electron and hole transport, leading to increased lifespan and efficiency of the OLEDs, with the emission layer including a host and dopant, optimizing light-emitting characteristics without significant increases in driving voltage.

Implementation Method 1

Holes provided from the first electrode may move to the emission layer through the hole transport region, and electrons provided from the second electrode may move to the emission layer through the electron transport region. The holes and the electrons are then recombined in the emission layer to produce excitons. These excitons change from an excited state to a ground state to thereby generate light.

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Implementation Method 2

the organic layer includes a host and dopant, optimizing light-emitting characteristics with fluorescent and phosphorescent characteristics

Methodology Applied
Scientific EffectPhosphorescence: Phosphorescence

Data Source

PatentUS10230054B2Organic light-emitting device
Publication Date: 2019.03.12 SAMSUNG DISPLAY CO LTD
  • US10230054B2 patent drawing
  • US10230054B2 patent drawing
  • US10230054B2 patent drawing

AI summary

An organic light-emitting device includes: a first electrode; a second electrode facing the first electrode; and an organic layer between the first electrode and the second electrode, the organic layer including an emission layer, wherein the organic layer includes a first compound and a second compound. The organic light-emitting device may have a high efficiency and long lifespan.