OLED Emitting Layer Host-Dopant Design for Color Purity

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Solution Overview

Problem

Organic light emitting diodes face issues with efficiency, lifespan, and color purity due to intermolecular interactions and the limitations of single-material emitting layers, necessitating the development of stable and efficient host materials for the emitting layer to balance charge and enhance thermal stability.

Innovation Solution

An organic electronic element comprising a compound represented by specific formulas, integrated into the emitting layer to reduce driving voltage, improve luminous efficiency, and enhance color purity and stability, utilizing a multi-layered structure with charge generation layers to optimize energy transfer and interfacial properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Device complexity

If a single material is used as a light emitting material, then the device structure is simple, but the maximum emission wavelength shifts to longer wavelength, lowering color purity and reducing device efficiency

Engineering Contradiction:
Improveemitting layer structureVSAvoidcolor purity
Core Design Contradiction:
Device complexityVSManufacturing precision

Solution Approach 1:

The patent employs a host/dopant composite material system where the emitting layer consists of a host material (Formula 1) combined with a dopant material (Formula 2 or 3). This composite approach allows the host to provide structural support and energy transfer while the dopant determines the emission color, thereby maintaining color purity despite the complexity of using multiple materials.

Inventive Principle:
Principle #40Composite materials

2Productivity

If short-wavelength dopants are used to increase maximum luminous efficiency, then the overall device efficiency increases, but the x color coordinate becomes very low, reducing color purity

Engineering Contradiction:
Improveluminous efficiencyVSAvoidcolor purity
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent optimizes the energy level parameters of both host and dopant materials to achieve efficient energy transfer while maintaining desirable emission characteristics. By carefully selecting and adjusting the energy levels (HOMO/LUMO) of the host (Formula 1) and dopant (Formula 2 or 3), the system achieves high luminous efficiency without sacrificing color purity, resolving the trade-off between efficiency and color quality.

Inventive Principle:
Principle #35Parameter changes

3Productivity

If the driving voltage is increased to improve efficiency, then the luminous efficiency increases, but Joule heating causes crystallization of organic materials, shortening the lifespan

Engineering Contradiction:
Improvedevice efficiencyVSAvoiddevice lifespan
Core Design Contradiction:
ProductivityVSDuration of action of stationary object

Solution Approach 1:

The patent modifies the energy level parameters (HOMO/LUMO) and molecular structure of the organic materials to reduce Joule heating effects. The optimized host (Formula 1) and dopant (Formula 2 or 3) combinations enable efficient charge transport at lower driving voltages, reducing thermal stress and preventing crystallization, thereby extending device lifespan while maintaining efficiency.

Inventive Principle:
Principle #35Parameter changes

4Reliability

If the energy level and T1 value between each organic material layer are optimally combined, then long lifespan and high efficiency can be achieved simultaneously, but the material development complexity increases

Engineering Contradiction:
Improvedevice performanceVSAvoidmaterial optimization requirements
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent establishes specific energy level parameters for the host (Formula 1) and dopant (Formula 2 or 3) materials to ensure optimal energy transfer and charge balance. By defining target HOMO/LUMO energy levels and T1 values, the invention provides clear material design guidelines that simplify the optimization process while achieving high efficiency and long lifespan simultaneously.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution achieves high luminous efficiency, low driving voltage, and extended lifespan while improving color purity and stability by optimizing the organic material layer's energy levels and interfacial characteristics.

Implementation Method 1

excitons generated in the emitting layer are transported to the dopant to emit light with high efficiency

Methodology Applied
Scientific EffectEnergy transfer: Fluorescence

Implementation Method 2

organic light emitting phenomenon refers to a phenomenon that converts electric energy into light energy by using an organic material

Methodology Applied
Scientific EffectOrganic light emitting phenomenon: Electroluminescence

Implementation Method 3

crystallization of organic materials due to Joule heating generated during driving decreases

Methodology Applied
Scientific EffectJoule heating: Joule Heating

Data Source

PatentUS11980045B1Organic electric element including compound for organic electric element, and electronic device thereof
Publication Date: 2024.05.07 DUK SAN NEOLUX
  • US11980045B1 patent drawing
  • US11980045B1 patent drawing
  • US11980045B1 patent drawing

AI summary

Provided are an organic electronic element comprising an anode, a cathode, and an organic material layer between the anode and the cathode, and an electronic device comprising the organic electronic element, wherein the organic material layer comprises each compound represented by Formula 1, Formula 2, or Formula 3, thereby the driving voltage of the organic electronic element can be lowered and the luminous efficiency and lifespan can be improved.