Organic Light-Emitting Device Host and Dopant Materials

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Solution Overview

Problem

Current organic light-emitting devices face challenges in achieving optimal performance due to limitations in the selection of host and dopant materials for the emission layer, which affect the efficiency and color coordinates of the emitted light.

Innovation Solution

The use of specific host and dopant materials, represented by particular chemical formulas, in the emission layer of the organic light-emitting device, which include pyrrolidine-based cores, condensed polycyclic-based cores, and specific ligands, to enhance light emission efficiency and color coordinates.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If conventional host and dopant materials are used in the emission layer, then the device structure is simple, but the light emission efficiency and color coordinates are suboptimal

Engineering Contradiction:
Improvematerial selection simplicityVSAvoidlight emission efficiency
Core Design Contradiction:
Ease of manufactureVSProductivity

Solution Approach 1:

The patent changes the chemical structure parameters of host and dopant materials by introducing specific functional groups (pyrrolidine-based cores, condensed polycyclic-based cores) and adjusting molecular weights and compositions to optimize light emission efficiency and color coordinates

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates composite emission layer materials by combining specifically designed host materials with dopant materials containing metal complexes (Ir, Pt, Os, Eu, Tb, Tm, Rh) coordinated with specific ligands, achieving synergistic effects that improve overall device performance

Inventive Principle:
Principle #40Composite materials

2Loss of time

If conventional host and dopant materials are used in the emission layer, then the material selection process is fast, but the color coordinates of emitted light are suboptimal

Engineering Contradiction:
Improvematerial selection timeVSAvoidcolor coordinates precision
Core Design Contradiction:
Loss of timeVSManufacturing precision

Solution Approach 1:

The patent systematically adjusts molecular structure parameters including core types (pyrrolidine, condensed polycyclic), substituent groups, and metal center selection to precisely control the emission color coordinates while maintaining efficient development processes

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces specific functional groups and structural motifs at localized positions within the host and dopant molecules to precisely tune color emission properties without requiring complete redesign of entire material systems

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The proposed solution improves the light emission efficiency and color coordinates of the organic light-emitting device, leading to better performance and efficiency in light production.

Implementation Method 1

Holes injected from the first electrode may move to an emission layer via the hole transport region while electrons injected from the second electrode may move to an emission layer via the electron transport region. Carriers (e.g., the holes and the electrons) then recombine in the emission layer to generate excitons. When these excitons drop from an excited state to a ground state, light is emitted.

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS10826000B2Organic light-emitting device
Publication Date: 2020.11.03 SAMSUNG DISPLAY CO LTD
  • US10826000B2 patent drawing
  • US10826000B2 patent drawing
  • US10826000B2 patent drawing

AI summary

An organic light-emitting device includes: a first electrode; a second electrode; and an organic layer between the first electrode and the second electrode, the organic layer including an emission layer, wherein the emission layer includes a first host and a dopant, the first host is represented by one selected from Formulae 1 and 2, and the dopant is represented by Formula 7:Ar11(L11)a11-(R11)b11]n11  Formula 1Ar21(L21)a21-(R21)b21]n21  Formula 2M(L1)n71(L2)n72.  Formula 7The organic light-emitting device may have high efficiency and long lifespan and may show little change in the efficiency at an x-coordinate (CIEx) value of 0.21.