OLED Host Material Molecular Design for Low Voltage and Long Lifespan

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Solution Overview

Problem

Existing organic electroluminescent devices face challenges in achieving low driving voltage and long lifespan characteristics, particularly in green emission OLEDs.

Innovation Solution

A compound represented by Formula 1, and an organic electroluminescent material comprising this compound along with other compounds represented by Formulas 2 or 3, are used to enhance the performance of organic electroluminescent devices.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Use of energy by moving object

If conventional phosphorescent materials are used in OLEDs, then luminous efficiency is improved, but device lifespan and driving voltage characteristics deteriorate

Engineering Contradiction:
Improveluminous efficiencyVSAvoiddevice lifespan
Core Design Contradiction:
Use of energy by moving objectVSReliability

Solution Approach 1:

The patent modifies the molecular structure of host materials by introducing specific substituents (dibenzofuran, dibenzothiophene, triazine, carbazole derivatives) at defined positions to alter electronic and physical parameters. This structural parameter change enables the material to achieve both high luminous efficiency and extended device lifespan simultaneously, resolving the contradiction between these two performance metrics.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention employs composite host materials combining multiple functional moieties (electron-transporting triazine rings, hole-transporting carbazole groups, and stabilizing dibenzofuran/dibenzothiophene units) within a single molecular framework. This composite structure integrates the beneficial properties of different material classes, achieving both high efficiency and long operational stability.

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If conventional host materials are used, then device manufacturing is simplified, but driving voltage and lifespan performance deteriorate

Engineering Contradiction:
Improvedevice manufacturing simplicityVSAvoiddriving voltage and lifespan characteristics
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent introduces specific functional groups at precise positions within the host material molecule (e.g., electron-withdrawing triazine at certain positions, electron-donating carbazole at others) to create local electronic property variations. This local quality optimization enables fine-tuning of charge transport and recombination characteristics, achieving low driving voltage and long lifespan while maintaining manufacturing feasibility through established synthesis routes.

Inventive Principle:
Principle #3Local quality

3Device complexity

If standard organic electroluminescent materials are used, then device complexity is reduced, but performance characteristics deteriorate

Engineering Contradiction:
Improvematerial structure simplicityVSAvoidluminous efficiency and lifespan performance
Core Design Contradiction:
Device complexityVSProductivity

Solution Approach 1:

The designed host materials perform multiple functions simultaneously: they serve as electron and hole transport media, facilitate exciton generation and recombination, provide structural stability, and enable efficient energy transfer to phosphorescent dopants. This multi-functionality is achieved through integrating diverse functional moieties (triazine, carbazole, dibenzofuran, dibenzothiophene) into a single molecular architecture, maintaining relatively simple device structure while achieving superior performance.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The proposed solution enables the development of organic electroluminescent devices with improved characteristics, including low driving voltage, high luminous efficiency, and extended lifespan.

Implementation Method 1

organic electroluminescent device

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS20250154136A1Compound, and organic electroluminescent material and organic electroluminescent device comprising the same
Publication Date: 2025.05.15 DUPONT SPECIALTY MATERIALS KOREA LTD
  • US20250154136A1 patent drawing
  • US20250154136A1 patent drawing
  • US20250154136A1 patent drawing

AI summary

The present disclosure relates to a compound, and an organic electroluminescent material and an organic electroluminescent device comprising the same. By comprising the compound and/or the organic electroluminescent material according to the present disclosure, an organic electroluminescent device can be provided which has low driving voltage and/or high luminous efficiency and/or long lifespan characteristics compared to conventional organic electroluminescent devices.