OLED Host Materials Reducing Driving Voltage

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Solution Overview

Problem

Current organic electroluminescent devices face challenges in achieving low driving voltage, high luminous efficiency, and long lifespan, particularly for medium and large-sized OLED panels, with existing host materials not adequately addressing these requirements.

Innovation Solution

A combination of specific host materials represented by formulas 1 and 2, comprising various alkylene, arylene, and heteroarylene groups, are used in the light-emitting layer to enhance the performance of organic electroluminescent devices, allowing for improved efficiency and lifespan.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If conventional host materials are used in organic electroluminescent devices, then the device structure is simple and ease of manufacture is maintained, but driving voltage remains high, luminous efficiency is insufficient, and lifespan is limited

Engineering Contradiction:
Improveease of manufactureVSAvoiddriving voltage
Core Design Contradiction:
Ease of manufactureVSPower

Solution Approach 1:

The patent applies composite materials by combining multiple host compounds (compounds 1-1 to 1-6) with specific molecular structures containing electron-deficient cores and electron-rich substituents. This composite approach creates a synergistic effect that reduces driving voltage while maintaining ease of manufacture through solution processing and vacuum deposition methods.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent employs parameter changes by systematically varying molecular parameters such as the core structure (triphenylene, pyrene, perylene), substituent types (carbazole, triphenylamine, dibenzofuran), and their arrangements to optimize the host material properties. This enables tuning of HOMO/LUMO levels, charge transport, and exciton management to achieve lower driving voltage.

Inventive Principle:
Principle #35Parameter changes

2Productivity

If conventional host materials are used in organic electroluminescent devices, then manufacturing complexity is low, but luminous efficiency remains insufficient

Engineering Contradiction:
Improveluminous efficiencyVSAvoiddevice complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent applies local quality by designing host molecules with specific functional zones: electron-deficient cores for charge acceptance, electron-rich substituents for charge donation, and specific linkers for structural stability. This localized functional distribution optimizes charge transport and exciton management at specific molecular regions, enhancing luminous efficiency.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent employs segmentation by dividing the host molecule into distinct functional segments: core units (triphenylene, pyrene), substituent units (carbazole, triphenylamine), and linker units. This modular segmentation allows independent optimization of each segment's function while maintaining overall molecular stability and processability.

Inventive Principle:
Principle #1Segmentation

3Duration of action of stationary object

If conventional host materials are used in organic electroluminescent devices, then material selection is simple, but lifespan is limited

Engineering Contradiction:
ImprovelifespanVSAvoidmaterial selection
Core Design Contradiction:
Duration of action of stationary objectVSAdaptability or versatility

Solution Approach 1:

The patent applies beforehand cushioning by incorporating stabilizing structural features in the host material design, such as rigid aromatic cores and stable substituent groups that resist degradation. These pre-built protective structures cushion against operational stress, oxygen, and moisture, thereby extending device lifespan before failure occurs.

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

Solution Approach 2:

The patent employs this principle by using small molecular weight host compounds that can be easily replaced and processed. These molecularly discrete host materials offer convenient replacement and reprocessing capabilities, allowing optimization of lifespan through material replacement without requiring complex device disassembly.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of these host materials results in organic electroluminescent devices with reduced driving voltage and increased luminous efficiency, along with extended lifespan, as demonstrated by comparative examples showing improved performance metrics.

Implementation Method 1

An organic electroluminescent device (OLED) changes electric energy into light by applying electricity to an organic electroluminescent material

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS20220052271A1A plurality of host materials and organic electroluminescent device comprising the same
Publication Date: 2022.02.17 DUPONT SPECIALTY MATERIALS KOREA LTD
  • US20220052271A1 patent drawing
  • US20220052271A1 patent drawing
  • US20220052271A1 patent drawing

AI summary

The present disclosure relates to a plurality of host materials and an organic electroluminescent device comprising the same. By comprising the host materials according to the present disclosure, an organic electroluminescent device having low driving voltage and/or a high efficiency and/or long lifespan can be provided.