OLED Host Materials for Low Voltage and High Efficiency

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Solution Overview

Problem

Current organic electroluminescent devices face challenges in achieving low driving voltage, high luminous efficiency, and long lifespan, particularly for medium and large-sized OLED panels, with existing host materials not adequately addressing these performance criteria.

Innovation Solution

The development of an organic electroluminescent compound represented by a specific formula, along with a first and second host material, which are used in the organic electroluminescent device to enhance its performance by forming a light-emitting layer, thereby improving driving voltage, luminous efficiency, and lifespan.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Use of energy by moving object

If conventional host materials are used in OLED, then device structure is simple, but driving voltage is high and luminous efficiency is low

Engineering Contradiction:
Improveluminous efficiencyVSAvoidhost material structure
Core Design Contradiction:
Use of energy by moving objectVSDevice complexity

Solution Approach 1:

The patent employs composite host material systems combining formula 1 compounds with formula 2 compounds (such as mCP, TCTA, or TAPC) to achieve synergistic effects. This composite approach enables simultaneously high luminous efficiency and low driving voltage by leveraging the complementary properties of different host materials, resolving the contradiction between performance improvement and material complexity.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent systematically varies molecular parameters including substituent types (electron-donating or electron-withdrawing groups), substituent positions, and core structures in formula 1 compounds. By optimizing these molecular parameters, the invention achieves enhanced charge transport properties and energy level alignment, thereby improving luminous efficiency without requiring overly complex device structures.

Inventive Principle:
Principle #35Parameter changes

2Duration of action of stationary object

If conventional host materials are used in OLED, then manufacturing process is simple, but lifespan is short

Engineering Contradiction:
ImprovelifespanVSAvoidmaterial selection complexity
Core Design Contradiction:
Duration of action of stationary objectVSEase of manufacture

Solution Approach 1:

The patent optimizes molecular parameters such as introducing electron-donating groups (e.g., -N(R1)2, -O-R1) or electron-withdrawing groups (e.g., -CN, -F) at specific positions on the core structure. These parameter changes enhance material stability and device lifespan by improving charge distribution and reducing degradation, while maintaining manufacturability through conventional OLED fabrication processes.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

By combining formula 1 host materials with formula 2 host materials in composite systems, the patent achieves enhanced device lifespan through synergistic effects. The composite structure improves overall material stability and operational durability without requiring fundamentally new manufacturing techniques, thus balancing lifespan extension with ease of manufacture.

Inventive Principle:
Principle #40Composite materials

3Stress or pressure

If conventional host materials are used in OLED, then device structure is simple, but driving voltage is high

Engineering Contradiction:
Improvedriving voltageVSAvoidhost material molecular structure
Core Design Contradiction:
Stress or pressureVSDevice complexity

Solution Approach 1:

The patent modifies molecular parameters by introducing specific substituents and adjusting core structures in formula 1 compounds to optimize energy levels and charge transport. These parameter changes improve hole mobility and energy level alignment with adjacent layers, thereby reducing driving voltage requirements while maintaining reasonable molecular structural complexity.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The composite system combining formula 1 and formula 2 host materials creates synergistic effects that enhance charge transport properties. This composite approach reduces driving voltage by improving overall hole mobility and energy level matching, while the molecular structures remain based on established chemical frameworks that are not excessively complex.

Inventive Principle:
Principle #40Composite materials

4Use of energy by moving object

If conventional host materials are used in OLED, then material selection is simple, but luminous efficiency is low

Engineering Contradiction:
Improveluminous efficiencyVSAvoidhost material compatibility
Core Design Contradiction:
Use of energy by moving objectVSAdaptability or versatility

Solution Approach 1:

The patent designs formula 1 host materials with universal applicability by using versatile core structures (such as carbazole, triphenylamine derivatives) that can function as electron-donating units. These core structures can be combined with various substituents and paired with different formula 2 host materials (mCP, TCTA, TAPC), making the formula 1 compounds adaptable to multiple device configurations while maintaining high luminous efficiency.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

By systematically varying substituent parameters (electron-donating or electron-withdrawing groups, alkyl chains, aromatic rings) on the core structure, the patent creates a series of formula 1 compounds with different properties. This parameter optimization enables fine-tuning of energy levels and charge transport characteristics, improving luminous efficiency while maintaining broad compatibility with various dopants and device architectures.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The proposed solution results in an organic electroluminescent device with reduced driving voltage, increased luminous efficiency, and extended lifespan, outperforming conventional devices in these key performance metrics.

Implementation Method 1

An organic electroluminescent device (OLED) was first developed by Eastman Kodak in 1987, by using small aromatic diamine molecules and aluminum complexes as materials for forming a light-emitting layer

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS20220263031A1Organic electroluminescent compound, a plurality of host materials, and organic electroluminescent device comprising the same
Publication Date: 2022.08.18 DUPONT SPECIALTY MATERIALS KOREA LTD
  • US20220263031A1 patent drawing
  • US20220263031A1 patent drawing
  • US20220263031A1 patent drawing

AI summary

The present disclosure relates to an organic electroluminescent compound, a plurality of host materials, and an organic electroluminescent device comprising the same. By comprising an organic electroluminescent compound and/or a plurality of host materials according to the present disclosure, an organic electroluminescent device having low driving voltage and/or high luminous efficiency and/or long lifespan can be provided.