OLED Emissive Layer Co-evaporation Using Indolocarbazole Terphenyl Compounds

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Solution Overview

Problem

Current OLED devices require complex and costly fabrication processes due to the need for multiple evaporation sources and unstable co-evaporation of multiple components, which affects device performance.

Innovation Solution

Development of novel compounds with specific formulas (e.g., Formula I and Formula II) that can be premixed and co-evaporated with similar evaporation temperatures and mass loss rates, reducing the number of evaporation sources and stabilizing the composition of the emissive layer in OLEDs.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If multiple evaporation sources are used for co-evaporation of multiple components, then the composition of the emissive layer can be controlled, but the fabrication process becomes complex and costly

Engineering Contradiction:
Improvecomposition control of emissive layerVSAvoidfabrication process complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent combines multiple evaporation sources into a single evaporation source by using a mixture of compounds (Formula I and Formula II) that can be co-evaporated simultaneously. This merging approach maintains the ability to control emissive layer composition while significantly reducing fabrication process complexity and cost.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent uses composite material mixtures (specific compounds of Formula I and Formula II) as the evaporation source. These composite mixtures are designed to have compatible evaporation characteristics, allowing them to be co-evaporated in a single process step while maintaining stable and controlled composition in the resulting emissive layer.

Inventive Principle:
Principle #40Composite materials

2Stability of the object's composition

If multiple components are co-evaporated, then the emissive layer composition can be stabilized, but the co-evaporation process becomes unstable

Engineering Contradiction:
Improveemissive layer composition stabilityVSAvoidco-evaporation process stability
Core Design Contradiction:
Stability of the object's compositionVSReliability

Solution Approach 1:

The patent optimizes specific parameters of the compounds (Formula I and Formula II) including their molecular structure, evaporation temperature, and mass loss rate. By carefully selecting and adjusting these parameters, the compounds achieve similar evaporation characteristics that enable stable and reliable co-evaporation while maintaining consistent emissive layer composition.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent designs the compound mixture to achieve homogeneity in evaporation behavior. The compounds are selected to have matched evaporation temperatures and mass loss rates, creating a homogeneous evaporation process that stabilizes the co-evaporation and ensures uniform composition in the emissive layer.

Inventive Principle:
Principle #33Homogeneity

3Reliability

If multiple evaporation sources are used, then device performance can be optimized, but fabrication cost increases

Engineering Contradiction:
Improvedevice performanceVSAvoidfabrication cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent merges multiple evaporation sources into one by using a pre-mixed compound mixture (Formula I and Formula II). This single-source approach maintains device performance optimization through controlled composition while eliminating the need for multiple expensive evaporation sources, thereby reducing fabrication cost.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent performs preliminary mixing of the compounds (Formula I and Formula II) before evaporation. This preliminary action ensures the correct composition ratio is established in advance, allowing single-source evaporation to achieve the same performance optimization that would otherwise require multiple precisely controlled evaporation sources, thus reducing fabrication cost.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach simplifies the fabrication process, enhances the stability and performance of OLEDs by ensuring consistent composition and reduced complexity in the evaporation process, leading to improved efficiency and longer device lifetime.

Implementation Method 1

unstable co-evaporation of multiple components

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 2

OLEDs make use of thin organic films that emit light when voltage is applied across the device

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS20240081147A1Organic Electroluminescent Materials and Devices
Publication Date: 2024.03.07 UNIVERSAL DISPLAY CORP
  • US20240081147A1 patent drawing
  • US20240081147A1 patent drawing
  • US20240081147A1 patent drawing

AI summary

Compounds containing indolocarbazole and terphenyl building blocks are disclosed in this application. These compounds are useful for application in organic electroluminescent devices.