OLED Ink Composition for Uniform Film Formation

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Solution Overview

Problem

The existing ink compositions for organic light-emitting devices face challenges in forming stable and uniform films due to low solubility and high volatility of solvents, leading to phase separation and prolonged processing times, which hinder the formation of precise patterns in large-area RGB displays.

Innovation Solution

An ink composition is developed, comprising a compound represented by Formula 1 and a solvent represented by Formula 2, which enhances the solubility and boiling point of functional layer materials, allowing for increased solid content and stable film formation, preventing phase separation and enabling uniform film formation through controlled evaporation rates.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If solvents of ethers or hydrocarbons are used as main solvents, then the ink composition can be formulated, but the process time is prolonged due to low solubility for functional layer material and phase separation occurs during drying

Engineering Contradiction:
Improvesolid content of inkVSAvoidprocess time
Core Design Contradiction:
Quantity of substanceVSLoss of time

Solution Approach 1:

The patent changes the chemical parameters of the solvent by selecting compounds with specific molecular weight ranges (150-300 g/mol) and boiling point ranges (100-200°C), which fundamentally alters the solubility characteristics and drying behavior of the ink composition, enabling both high solid content and reasonable process time

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite solvent systems combining multiple ether or hydrocarbon solvents with complementary properties, where the synergistic effect of the solvent mixture provides both high solubility for functional layer materials and controlled evaporation rates, preventing phase separation while maintaining high solid content

Inventive Principle:
Principle #40Composite materials

2Quantity of substance

If solvents with low boiling point are used, then the solubility for functional layer material is improved, but the nozzle part is dried due to high volatility

Engineering Contradiction:
Improvesolubility for functional layer materialVSAvoidnozzle stability
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The patent optimizes the boiling point parameter of the solvent to fall within 100-200°C, which is high enough to prevent nozzle drying during storage and handling, yet low enough to ensure complete evaporation during the drying process, while maintaining excellent solubility for functional layer materials

Inventive Principle:
Principle #35Parameter changes

3Area of stationary object

If the area of the display is increased, then the display size is enlarged, but mask sagging phenomenon occurs making it difficult to manufacture RGB type OLED display

Engineering Contradiction:
Improvedisplay areaVSAvoidpattern formation accuracy
Core Design Contradiction:
Area of stationary objectVSManufacturing precision

Solution Approach 1:

The patent replaces the mechanical mask-based deposition system with a solution-based inkjet printing system, where the ink composition's controlled evaporation and uniform film formation properties enable precise pattern deposition over large areas without mask sagging, maintaining manufacturing precision regardless of display size

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

4Quantity of substance

If the number of drops is increased to obtain desired thickness, then the film thickness is sufficient, but it is difficult to obtain a flat profile

Engineering Contradiction:
Improvefilm thicknessVSAvoidfilm flatness
Core Design Contradiction:
Quantity of substanceVSManufacturing precision

Solution Approach 1:

The patent modifies the solvent's molecular weight and boiling point parameters to achieve optimal evaporation kinetics, where the controlled evaporation rate allows the ink to self-level and form flat profiles even when multiple drops are deposited, preventing coffee-ring effects and surface irregularities

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The ink composition achieves improved stability and uniformity in film formation, enabling the creation of flat and precise patterns in large-area RGB displays, with enhanced discharge stability and solvent resistance, thus supporting efficient manufacturing of organic light-emitting devices.

Implementation Method 1

the solubility of a solvent for a functional layer material is high, so that it is possible to increase the content of the functional layer material in the ink composition

Methodology Applied
Scientific EffectSolvation: Solvation

Implementation Method 2

a stable film cannot be formed because the phase separation occurs during the drying

Methodology Applied
Scientific EffectEvaporation: Evaporation

Data Source

PatentUS11515476B2Ink composition and method for manufacturing organic light emitting device
Publication Date: 2022.11.29 LG CHEM LTD
  • US11515476B2 patent drawing
  • US11515476B2 patent drawing
  • US11515476B2 patent drawing

AI summary

The present specification relates to an ink composition including: a compound represented by Formula 1; and a solvent represented by the Formula 2, and a method for manufacturing an organic light emitting device formed by using the ink composition.