OLED Inkjet Printing Uniformity via Ashing and Lyophobic Layer
Find Innovative SolutionsGenerate Solutions
Solution Overview
Problem
The conventional pixel defining layer structure in OLED display devices causes a coffee ring effect during the ink-jet printing process, resulting in a thin center and a too thick edge of the thin film, leading to uneven luminance and reduced material utilization efficiency.
Innovation Solution
An ink-jet printing method is employed where a first lyophobic ink is printed within a pixel, forming a thin film that covers the lyophilic portion of the pixel defining layer, and the central portion of this film is removed using an ashing process, followed by printing a second organic functional ink to form a uniform thin film, reducing the pinning effect and improving topography.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Manufacturing precision
If conventional pixel defining layer structure is used, then the ink droplet can be contained within the pixel, but the coffee ring effect occurs causing non-uniform thin film topography
Solution Approach 1:
The patent applies preliminary action by performing an ashing treatment on the pixel defining layer before inkjet printing. This pre-treatment modifies the surface properties of the pixel defining layer to reduce the pinning effect on the contact line, thereby preventing the coffee ring effect from occurring during the subsequent ink drying process. The ashing treatment creates a more uniform surface that allows for even solvent evaporation and uniform thin film formation.
Solution Approach 2:
The patent changes the surface parameters of the pixel defining layer through ashing treatment. This treatment alters the surface energy, roughness, and chemical composition of the pixel defining layer, transforming it from a state that promotes contact line pinning to one that allows contact line retraction. This parameter change eliminates the conditions necessary for coffee ring effect formation while maintaining the pixel defining layer's ability to contain the ink droplet.
2Manufacturing precision
If the contact line is pinned at the edge of the pixel defining layer, then the ink is contained within the pixel, but the edge portion accumulates excessive solute resulting in thick edges
Solution Approach 1:
The ashing treatment is applied as a preliminary action to modify the pixel defining layer surface before ink deposition. This pre-treatment creates a surface that does not strongly pin the contact line, allowing the contact line to retract inward during drying. This prevents the progressive accumulation of solute at the edge that would otherwise occur due to continuous contact line pinning and capillary compensation flow.
Solution Approach 2:
The patent converts the potentially harmful pinning effect into a beneficial retraction effect. By modifying the pixel defining layer surface through ashing, the originally harmful strong pinning that causes edge accumulation is transformed into a controlled retraction behavior. The contact line now moves inward during drying, distributing solute more uniformly across the pixel area rather than accumulating at the edges.
3Reliability
If the pixel defining layer has strong lyophobic property to prevent ink mixing, then the contact line pinning effect increases, but the coffee ring effect is enhanced
Solution Approach 1:
The ashing treatment changes the surface parameters of the pixel defining layer to achieve a balance between lyophobic properties and contact line behavior. The treatment modifies surface energy and roughness to maintain ink isolation between pixels while reducing the excessive pinning effect. This creates an optimal surface state that prevents both ink mixing and coffee ring effect formation simultaneously.
Solution Approach 2:
The patent applies local quality by creating a pixel defining layer surface with spatially varying properties through ashing treatment. The surface is modified to have appropriate lyophobic characteristics at the pixel boundaries for ink containment, while the overall surface properties are adjusted to reduce contact line pinning. This local differentiation allows the structure to simultaneously achieve ink isolation and uniform thin film formation.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
This method effectively reduces the coffee ring effect, achieving a uniform thin film topography and improving the flatness of the OLED display device, thereby enhancing the display effect and material utilization.
Implementation Method 1
printing a first ink within a groove defined by a pixel defining layer, so that the first ink forms a first thin film by a drying process
Implementation Method 2
removing a central portion of the first thin film, the central portion being located at the bottom of the groove
Implementation Method 3
printing a second ink into the groove covered with the first thin film, so that the second ink forms a second thin film by the drying process
Implementation Method 4
the lyophobic first ink component printed within the pixel reduces the pinning effect of the lyophilic portion of an inner surface of the pixel defining layer on the second ink component
Implementation Method 5
there exists a concentration gradient (difference) between the central and edge portions, thereby causing the capillary compensation phenomenon that the solvent flows from the central portion to the edge portion
Implementation Method 6
there exists inside the ink droplet a Marangoni convection phenomenon in the inverse direction
Data Source
AI summary
Embodiments of the present disclosure provide an ink-jet printing method and a manufacturing method of an OLED display device. The ink-jet printing method includes printing a first ink within a groove defined by a pixel defining layer, such that the first ink forms a first thin film by a drying process, the first thin film covering an inner surface of a lyophilic portion of the pixel defining layer; removing a central portion of the first thin film, the central portion being located at the bottom of the groove; and printing a second ink into the groove covered with the first thin film, such that the second ink forms a second thin film by the drying process.


