Organic Light Emitting Device Intermediate Layers Charge Balance

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Solution Overview

Problem

Conventional organic light emitting devices have relatively poor lifetime characteristics due to the imbalance in the flow speeds of holes and electrons, which leads to deterioration during operation.

Innovation Solution

Incorporating a first intermediate layer with a first host and dopant, a second intermediate layer with only the dopant, and a third intermediate layer with a second host and dopant, between the electrodes and the emission layer, to balance the flow speeds of holes and electrons, thereby enhancing the device's lifetime.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional organic light emitting device structure is used, then device simplicity is maintained, but lifetime characteristics deteriorate due to imbalance in hole and electron flow speeds

Engineering Contradiction:
Improvelifetime characteristicsVSAvoidintermediate layer structure
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent divides the intermediate layer into three distinct sub-layers (first, second, and third intermediate layers) with different material compositions. The first intermediate layer contains a first host and first dopant, the second intermediate layer contains only dopant without host, and the third intermediate layer contains a second host and first dopant. This segmentation allows each sub-layer to contribute differently to charge transport, balancing hole and electron flow speeds to improve lifetime characteristics.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Each intermediate layer is assigned specific local properties: the first intermediate layer provides hole transport with host-dopant complex, the second intermediate layer provides dopant-only region for charge balance, and the third intermediate layer provides additional host-dopant interaction. This local quality differentiation optimizes charge carrier flow in different regions of the device.

Inventive Principle:
Principle #3Local quality

2Duration of action of stationary object

If intermediate layers are added to balance charge flow, then lifetime is improved, but device structure complexity increases

Engineering Contradiction:
Improvedevice lifetimeVSAvoidlayer structure
Core Design Contradiction:
Duration of action of stationary objectVSDevice complexity

Solution Approach 1:

The intermediate region is segmented into three functional sub-layers, each with specific material compositions (host-dopant, dopant-only, host-dopant). This segmentation enables precise control over charge transport properties without requiring complete redesign of the entire device structure.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The three intermediate layers act as intermediary structures between the electrodes and emission layer, mediating the charge transport process. The dopant-containing layers specifically facilitate balanced hole and electron flow, serving as intermediaries that resolve the charge imbalance problem without requiring fundamental changes to the device architecture.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Reliability

If dopant-only layer is introduced, then charge flow balance is achieved, but manufacturing complexity increases

Engineering Contradiction:
Improvecharge flow balanceVSAvoidlayer deposition process
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent varies the compositional parameters across the three intermediate layers: the first and third layers contain host-dopant complexes with specific doping concentrations, while the second layer contains dopant only. This parameter variation (host presence/absence, dopant concentration) enables precise control of charge transport properties.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The intermediate structure uses composite material combinations: host materials combined with dopant materials in specific ratios and configurations. The dopant-only second intermediate layer represents a unique composite configuration that optimizes charge balance while maintaining manufacturability through sequential deposition processes.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The balanced flow of holes and electrons results in increased lifetime and improved luminescence characteristics without a substantial increase in operating voltage, as demonstrated by the comparison with conventional devices in the provided examples.

Implementation Method 1

a first intermediate layer including a first host and a first dopant, a second intermediate layer including the first dopant, and a third intermediate layer including a second host and the first dopant, between a first electrode and an emission layer

Methodology Applied
Scientific EffectCharge transport: Conduction (electrical)

Data Source

PatentUS8911884B2Organic light emitting device
Publication Date: 2014.12.16 SAMSUNG DISPLAY CO LTD
  • US8911884B2 patent drawing
  • US8911884B2 patent drawing
  • US8911884B2 patent drawing

AI summary

An organic light emitting device includes a substrate; a first electrode; a second electrode; and an organic layer including an emission layer between the first electrode and the second electrode. The organic layer includes a first intermediate layer including a first host and a first dopant, a second intermediate layer including the first dopant, and a third intermediate layer including a second host and the first dopant interposed between the first electrode and the emission layer. The organic light emitting device has a long lifetime.