OLED Layer Composition for Charge Balance and Longer Lifespan

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Solution Overview

Problem

Existing organic light-emitting devices face challenges in achieving high efficiency and long lifespan due to limitations in charge transport and interfacial properties between the hole transport region, emission layer, and electron transport region.

Innovation Solution

The organic light-emitting device incorporates specific compounds in the hole transport region, emission layer, and electron transport region, including a fluorescent host and dopant, and nitrogen-containing heterocyclic groups, which facilitate improved charge movement and interfacial stability, thereby enhancing efficiency and lifespan.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional organic light-emitting devices are used, then basic light emission is achieved, but efficiency and lifespan are limited due to poor charge transport and interfacial properties

Engineering Contradiction:
Improveemission efficiencyVSAvoidlifespan
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent applies local quality by using different compounds with specific properties in different regions: the hole transport region uses compounds with hole-transporting capabilities, the emission layer uses fluorescent host and dopant compounds for light emission, and the electron transport region uses compounds with electron-transporting capabilities. This regional differentiation optimizes charge transport and interfacial properties at each interface, thereby improving both emission efficiency and device lifespan.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent employs composite materials by combining multiple compounds in each functional layer. Specifically, the emission layer comprises a fluorescent host compound and a fluorescent dopant compound, while transport layers contain multiple compounds with complementary properties. This composite approach enhances charge transport efficiency and interfacial stability, resolving the contradiction between efficiency and lifespan.

Inventive Principle:
Principle #40Composite materials

2Productivity

If charge transport is improved through compound selection, then emission efficiency increases, but device complexity increases due to multiple compounds in each layer

Engineering Contradiction:
Improveemission efficiencyVSAvoidnumber of compounds
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent applies universality by selecting compounds that can perform multiple functions. For example, certain compounds in the transport regions not only facilitate charge transport but also provide good interfacial properties with adjacent layers. The fluorescent host compound serves both as a matrix for dopant embedding and as a charge transport medium. This multi-functionality reduces the need for separate specialized materials, thereby managing complexity while maintaining high emission efficiency.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The proposed structure improves emission efficiency, reduces triplet exciton transition, and extends the lifespan of the organic light-emitting device by facilitating charge transport and interfacial stability.

Implementation Method 1

the second compound included in the emission layer is a fluorescent host and the third compound included in the emission layer is a fluorescent dopant

Methodology Applied
Scientific EffectFluorescence: Fluorescence

Implementation Method 2

the fifth compound includes, as a ring-forming moiety, a nitrogen-containing heterocyclic group including *═N—*′

Methodology Applied
Scientific EffectElectron delocalization:

Data Source

PatentUS11856842B2Organic light-emitting device
Publication Date: 2023.12.26 SAMSUNG DISPLAY CO LTD
  • US11856842B2 patent drawing
  • US11856842B2 patent drawing
  • US11856842B2 patent drawing

AI summary

An organic light-emitting device includes: a first electrode; a second electrode facing the first electrode; an emission layer between the first electrode and the second electrode; a hole transport region between the first electrode and the emission layer; and an electron transport region between the emission layer and the second electrode, wherein the hole transport region includes a first compound, the emission layer includes a second compound and a third compound, and the electron transport region includes a fourth compound and a fifth compound. An organic light-emitting device according to the one or more embodiments may have high efficiency and long lifespan.