OLED Electron-Transport Layer Refractive Index Matching

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Solution Overview

Problem

Organic light-emitting devices (OLEDs) face low outcoupling efficiency due to refractive index differences between layers, leading to reduced efficiency in light emission.

Innovation Solution

Incorporating an electron-transport layer with a specific refractive index range, utilizing an organic compound and an alkali metal complex, to optimize light extraction efficiency by matching the refractive indices of the organic compound and the metal complex, thereby reducing reflection losses.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If a conventional electron-transport layer is used in the EL layer, then the device structure is simple, but light extraction efficiency is reduced due to reflection caused by refractive index differences between layers

Engineering Contradiction:
Improvedevice structure simplicityVSAvoidlight extraction efficiency
Core Design Contradiction:
Ease of manufactureVSLoss of energy

Solution Approach 1:

The patent changes the refractive index parameter of the electron-transport layer by selecting specific organic compounds with refractive indices between 1.50 and 1.75. This parameter optimization reduces the refractive index difference between adjacent layers, thereby minimizing reflection losses and improving light extraction efficiency without complicating the device structure

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite materials by combining specific organic compounds (such as mCP, TCTA, TAPC) with alkali metal complexes in the electron-transport layer. This composite approach allows simultaneous achievement of appropriate refractive index, good electron transport properties, and improved light extraction efficiency

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If the refractive index of the electron-transport layer is not optimized, then material selection is easier, but reflection losses increase and light emission efficiency decreases

Engineering Contradiction:
Improvematerial selection easeVSAvoidlight emission efficiency
Core Design Contradiction:
Ease of manufactureVSProductivity

Solution Approach 1:

The patent establishes a specific refractive index range (1.50-1.75) for the electron-transport layer as a design parameter. This parameter specification guides material selection while ensuring optimal light extraction. The patent provides concrete material examples (mCP, TCTA, TAPC) that fall within this range, making it easier for manufacturers to select appropriate materials without compromising light emission efficiency

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution enhances light emission efficiency by minimizing reflection and increasing the extraction of light from the OLEDs, resulting in improved performance with low power consumption and reduced driving voltage.

Implementation Method 1

the attenuation due to reflection which is caused by a difference in refractive index between adjacent layers is a main cause of a reduction in the efficiency of a light-emitting device

Methodology Applied
Scientific EffectRefraction: Refraction

Implementation Method 2

the attenuation due to reflection which is caused by a difference in refractive index between adjacent layers

Methodology Applied
Scientific EffectReflection: Reflection

Implementation Method 3

Light-emitting devices (organic EL devices) utilizing electroluminescence (EL) of organic compounds

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS20240164134A1Light-Emitting Device, Metal Complex, Light-Emitting Apparatus, Electronic Apparatus, And Lighting Device
Publication Date: 2024.05.16 SEMICON ENERGY LAB CO LTD
  • US20240164134A1 patent drawing
  • US20240164134A1 patent drawing
  • US20240164134A1 patent drawing

AI summary

A light-emitting device with high emission efficiency is provided. The light-emitting device includes an anode, a cathode, and an EL layer positioned between the anode and the cathode. The EL layer includes a light-emitting layer and an electron-transport layer; the light-emitting layer includes a light-emitting material; the electron-transport layer includes an organic compound having an electron-transport property and a metal complex of an alkali metal; the ordinary refractive index of the organic compound having an electron-transport property in a peak wavelength of light emitted from the light-emitting material is greater than or equal to 1.50 and less than or equal to 1.75; and the ordinary refractive index of the metal complex of an alkali metal in the peak wavelength of the light emitted from the light-emitting material is greater than or equal to 1.45 and less than or equal to 1.70.