Organometallic Ligand Complexes for Saturated Color OLEDs

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Solution Overview

Problem

Current organic light-emitting diode (OLED) technologies face challenges in achieving saturated colors for full-color displays, particularly in producing red, green, and blue pixels, which are essential for industry standards, and there is a need for improved materials that can efficiently emit light with desired color characteristics.

Innovation Solution

A compound comprising a specific ligand LA of Formula I, which is coordinated to a metal M with an atomic mass of at least 40, is used in the organic layer of OLEDs. This ligand is designed to enhance the photoactive properties and is capable of forming tridentate, tetradentate, pentadentate, or hexadentate complexes, improving the emission characteristics.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional organic materials are used in OLEDs, then the device structure can be simple and fabrication can be easier, but the color saturation and emission characteristics cannot meet industry standards for full-color displays

Engineering Contradiction:
Improvecolor saturationVSAvoidligand structure complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent applies parameter changes by systematically varying the ligand structure parameters (different substituents at positions R1-R6, different core moieties A and B, different dentates) to achieve the desired color saturation and emission characteristics while meeting industry standards for full-color displays

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite materials by creating organometallic compounds with complex ligand structures that combine multiple functional groups and moieties (moiety A, moiety B, various substituents) to achieve both the required color saturation and the necessary emission properties for OLED applications

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If simple ligand structures are used, then the compound synthesis can be easier and less complex, but the light emission properties and color characteristics are insufficient for saturated color display

Engineering Contradiction:
Improvecompound synthesis easeVSAvoidlight emission quality
Core Design Contradiction:
Ease of manufactureVSIllumination intensity

Solution Approach 1:

The patent uses parameter changes by modifying ligand structure parameters (substituents R1-R6, core moieties, dentate variations) to optimize both the synthesis feasibility and the light emission quality, achieving a balance between ease of manufacture and saturated color emission

Inventive Principle:
Principle #35Parameter changes

3Reliability

If conventional materials are used, then cost can be lower and fabrication can be simpler, but performance advantages for saturated color emission are not achieved

Engineering Contradiction:
Improveemission performanceVSAvoidmaterial structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent applies parameter changes by systematically varying the organometallic compound parameters (metal center, ligand substituents, core moieties) to achieve reliable saturated color emission performance while managing the complexity of material structure

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of the compound with the ligand LA in OLEDs leads to enhanced light emission properties, enabling the production of saturated colors and improved performance in OLED devices, aligning with industry standards for full-color displays.

Implementation Method 1

OLEDs make use of thin organic films that emit light when voltage is applied across the device

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Implementation Method 2

One application for phosphorescent emissive molecules is a full color display

Methodology Applied
Scientific EffectPhosphorescence: Phosphorescence

Data Source

PatentUS20240315125A1Organic electroluminescent materials and devices
Publication Date: 2024.09.19 UNIVERSAL DISPLAY CORP
  • US20240315125A1 patent drawing
  • US20240315125A1 patent drawing
  • US20240315125A1 patent drawing

AI summary

A compound comprising a first ligand LA of Formula I,is provided. In Formula I, moiety A is a monocyclic ring or a polycyclic fused ring system; K1 and K2 are independently a single bond or a linker; Z1 and Z2 are C or N; each RA, RB, and RC is hydrogen or a General Substituent; at least one RB and at least one RC are not hydrogen or deuterium; LA is coordinated to a metal M, having an atomic mass of at least 40. Formulations, OLEDs, and consumer products comprising the compound are also provided.