OLED Mixed Layer with Anthracene and Amine Compounds

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Current organic light-emitting devices face challenges in balancing electron and hole transport, leading to reduced efficiency and lifespan, along with higher driving voltage due to the lack of effective compounds with both electron and hole transportability.

Innovation Solution

Incorporating a mixed layer with a combination of an anthracene-based compound and an amine-based compound, where the anthracene-based compound provides excellent electron transportability and the amine-based compound enhances hole transportability, creating a balanced layer that improves efficiency and lifespan while maintaining low driving voltage.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional organic light-emitting devices use separate electron transport and hole transport regions, then device structure is simplified, but the balance between electron and hole transport deteriorates leading to reduced efficiency and lifespan

Engineering Contradiction:
Improvedevice lifespanVSAvoidlayer structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent merges electron transport and hole transport functions into a single mixed layer by combining an anthracene-based compound (providing electron transport capability) and an amine-based compound (providing hole transport capability). This unified approach allows both electron and hole transport to occur simultaneously within the same layer, improving transport balance and device reliability without requiring separate transport regions.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent uses a composite material system consisting of two different organic compounds with complementary transport properties. The anthracene-based compound contributes electron transportability while the amine-based compound contributes hole transportability, creating a composite layer that achieves balanced dual-carrier transport within a single material system.

Inventive Principle:
Principle #40Composite materials

2Productivity

If conventional devices lack compounds with both electron and hole transportability, then material selection is easier, but efficiency and lifespan are reduced due to unbalanced carrier transport

Engineering Contradiction:
Improvedevice efficiencyVSAvoidcompound composition complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The mixed layer achieves multi-functionality by enabling both electron transport and hole transport within the same layer. The anthracene-based compound provides electron transport capability while the amine-based compound provides hole transport capability, allowing the single mixed layer to perform multiple transport functions that traditionally required separate regions.

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Power

If devices use traditional single-layer structures, then manufacturing is simpler, but driving voltage increases due to unbalanced carrier transport

Engineering Contradiction:
Improvedriving voltageVSAvoidlayer fabrication simplicity
Core Design Contradiction:
PowerVSEase of manufacture

Solution Approach 1:

The patent changes the chemical composition parameters of the organic layer by selecting specific compounds with appropriate energy levels and transport properties. The anthracene-based compound and amine-based compound are chosen to have complementary HOMO and LUMO levels that facilitate balanced carrier transport, thereby reducing the energy barrier and driving voltage required for device operation.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of a mixed layer with these compounds improves the balance between electrons and holes, enhancing the efficiency and lifespan of the organic light-emitting device while reducing driving voltage.

Implementation Method 1

the first compound includes an anthracene-based compound represented by Formula 1... wherein the first compound provides excellent electron transportability

Methodology Applied
Scientific EffectElectron transport: Conduction (electrical)

Implementation Method 2

the second compound includes an amine-based compound represented by Formula 2... wherein the amine-based compound enhances hole transportability

Methodology Applied
Scientific EffectHole transport: Conduction (electrical)

Implementation Method 3

Carriers, such as holes and electrons, recombine in the emission layer to produce excitons. These excitons transit (e.g., transition or relax) from an excited state to a ground state, thereby generating light

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS11316125B2Organic light-emitting device and display apparatus including the same
Publication Date: 2022.04.26 SAMSUNG DISPLAY CO LTD
  • US11316125B2 patent drawing
  • US11316125B2 patent drawing
  • US11316125B2 patent drawing

AI summary

An organic light-emitting device includes: a first electrode; a second electrode; and an organic layer between the first electrode and the second electrode, wherein the organic layer comprises an emission layer, a mixed layer, and a hole transport region, the hole transport region is between the emission layer and the first electrode, the mixed layer is between the hole transport region and the emission layer, and comprises a first compound and a second compound, the first compound comprises an anthracene-based compound represented by Formula 1, and the second compound comprises an amine-based compound represented by Formula 2. A display apparatus includes the organic light-emitting device.