OLED Encapsulation with Moisture Absorbent Layers

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Solution Overview

Problem

Organic light emitting displays face instability due to moisture and oxygen exposure, which deteriorates device characteristics and shortens lifespan, as the reactive metal cathode and organic material layers are susceptible to oxidation and moisture absorption.

Innovation Solution

An organic light emitting display is designed with a substrate, an organic light emitting diode, an encapsulation substrate, a filler layer, and two encapsulation layers, where the filler and second encapsulation layers include a moisture absorbent, with a specific weight percentage relationship (B-A>0) to effectively suppress moisture and oxygen, using polymers and sealants like epoxy-based resins, and moisture absorbents such as CaO and BaO.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a glass or metal cap is used for encapsulation, then moisture and oxygen protection is improved, but device complexity and manufacturing difficulty increase

Engineering Contradiction:
Improvemoisture and oxygen protectionVSAvoidencapsulation structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent replaces rigid glass or metal caps with flexible organic encapsulation layers (first and second encapsulation layers) that seal the organic light emitting diode. These thin film layers provide effective moisture and oxygen barrier protection while simplifying the encapsulation structure and reducing manufacturing complexity compared to traditional rigid cap approaches.

Inventive Principle:
Principle #30Flexible shells and thin films

Solution Approach 2:

The patent employs composite encapsulation structures combining organic encapsulation layers with inorganic filler layers containing moisture absorbents. This composite approach integrates the barrier properties of organic materials with the moisture-absorbing capabilities of inorganic substances, achieving superior protection without requiring complex glass or metal encapsulation structures.

Inventive Principle:
Principle #40Composite materials

2Reliability

If the cathode is formed with reactive metal materials, then work function and emission efficiency are improved, but susceptibility to oxidation and moisture absorption increases

Engineering Contradiction:
Improveemission efficiencyVSAvoidoxidation and moisture absorption
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent creates an inert protective environment by filling the encapsulation structure with nitrogen gas and incorporating nitrogen-containing polymer compounds in the encapsulation layers. This inert atmosphere prevents oxidation of the reactive metal cathode while maintaining high emission efficiency, effectively isolating the cathode from harmful oxygen and moisture.

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

Solution Approach 2:

The patent incorporates moisture absorbent materials (such as calcium oxide, barium oxide, or clay) within the encapsulation structure that actively capture and neutralize moisture and oxygen. These materials convert the harmful effects of moisture and oxygen into beneficial moisture-trapping action, protecting the reactive cathode while maintaining device performance.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

3Ease of manufacture

If organic material layers are used below the cathode, then device flexibility and manufacturing ease are improved, but susceptibility to rapid deterioration from oxygen and moisture exposure increases

Engineering Contradiction:
Improvedevice flexibilityVSAvoidstability against oxidation
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent enhances organic encapsulation layers by incorporating inorganic filler particles (moisture absorbents such as calcium oxide, barium oxide, or clay) within the organic polymer matrix. This composite structure maintains the flexibility and manufacturing advantages of organic materials while adding superior moisture and oxygen barrier properties through the inorganic fillers, preventing rapid deterioration.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent introduces nitrogen-containing polymer compounds as intermediary protective layers between the organic light emitting diode and the external environment. These intermediary layers provide enhanced chemical resistance and barrier properties, protecting the organic material layers from direct exposure to oxygen and moisture while maintaining device flexibility.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides excellent stability by maintaining a low moisture transmittance rate, significantly increasing the lifespan of the organic light emitting display by effectively blocking moisture and oxygen, as demonstrated by the improved water vapor transmission rate and extended lifespan in comparison to comparative examples.

Implementation Method 1

the filler layer and the second encapsulation layer include a moisture absorbent

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Implementation Method 2

sealing the substrate and the encapsulation substrate together

Methodology Applied
Scientific EffectPhysical containment: Physical Containment

Data Source

PatentUS7956538B2Organic light emitting display
Publication Date: 2011.06.07 SAMSUNG DISPLAY CO LTD
  • US7956538B2 patent drawing
  • US7956538B2 patent drawing

AI summary

An organic light emitting display includes a substrate; an organic light emitting diode on one surface of the substrate; an encapsulation substrate located opposite and substantially parallel to the substrate with the organic light emitting diode therebetween; a filler layer on one surface of the encapsulation substrate facing the substrate; a first encapsulation layer located between the encapsulation substrate and the substrate and sealing the substrate and the encapsulation substrate together; and a second encapsulation layer located adjacent to the first encapsulation layer and between the encapsulation substrate and the substrate, wherein the filler layer and the second encapsulation layer include a moisture absorbent.